{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:31:29Z","timestamp":1786977089273,"version":"build-2736575974"},"reference-count":46,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2023,2,8]],"date-time":"2023-02-08T00:00:00Z","timestamp":1675814400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2023,3,14]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The present study reports on the photocatalytic oxidation of butanols to butanal\/butanone using thin film form of facet\u2010dependent nano\u2010Pd supported on commercial TiO\n                    <jats:sub>2<\/jats:sub>\n                    under one\u2010sun condition and demonstrates the generic nature. Pd\u2010nanocube (Pd\n                    <jats:sub>NC<\/jats:sub>\n                    (100)), Pd\u2010truncated octahedron (Pd\n                    <jats:sub>TO<\/jats:sub>\n                    (100) and (111)), polycrystalline (Pd\n                    <jats:sub>PC<\/jats:sub>\n                    ), and their counterparts with half\u2010a\u2010monolayer Pt\u2010coated on Pd (0.5\u03b8\n                    <jats:sub>Pt<\/jats:sub>\n                    \u2010Pd)) have been used as co\u2010catalyst. A potentially scalable thin film form of Pd\/TiO\n                    <jats:sub>2<\/jats:sub>\n                    photocatalyst, prepared by drop\u2010casting method, has been employed to study oxidation of n\u2010butanol, 2\u2010butanol, and iso\u2010butanol to corresponding aldehyde\/ketone. 100% selectivity is demonstrated to respective aldehyde\/ketone with any catalyst used in the present study with varying degree of butanols conversion by NMR. 0.5\u03b8\n                    <jats:sub>Pt<\/jats:sub>\n                    \u2010Pd\n                    <jats:sub>TO<\/jats:sub>\n                    \/TiO\n                    <jats:sub>2<\/jats:sub>\n                    shows the highest conversion of 2\u2010butanol to butanone (13.6% in 4\u2005h). Continuous 10\u2005h of reaction with the most active 0.5\u03b8\n                    <jats:sub>Pt<\/jats:sub>\n                    \u2010Pd\n                    <jats:sub>TO<\/jats:sub>\n                    \/P25 catalyst demonstrates 31% conversion of 2\u2010butanol to butanone, and catalyst recyclability has been demonstrated. The present protocol can be scalable to large scales to maximize the conversion in direct sunlight. Due to its generic nature, the current method can also be applied to many other alcohols and substrate molecules.\n                  <\/jats:p>","DOI":"10.1002\/asia.202201239","type":"journal-article","created":{"date-parts":[[2023,1,30]],"date-time":"2023-01-30T13:59:00Z","timestamp":1675087140000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Selective and Generic Photocatalytic Oxidation of Alcohol with Pd\u2212TiO\n                    <sub>2<\/sub>\n                    Thin Films: Butanols to Butanal\/Butanone with Different Morphologies of Pd and 0.5\u03b8\n                    <sub>Pt<\/sub>\n                    \u2010Pd Counterparts"],"prefix":"10.1002","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1968-1320","authenticated-orcid":false,"given":"Kranti N.","family":"Salgaonkar","sequence":"first","affiliation":[{"name":"Catalysis and Inorganic Chemistry Division CSIR-National Chemical Laboratory  Dr. Homi Bhabha Road Pune 411 008 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sandip R.","family":"Kale","sequence":"additional","affiliation":[{"name":"Catalysis and Inorganic Chemistry Division CSIR-National Chemical Laboratory  Dr. Homi Bhabha Road Pune 411 008 India"},{"name":"Currently at Department of Chemistry Yogeshwari Mahavidyalaya, Ambajogai  Beed 431 517 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Naresh","family":"Nalajala","sequence":"additional","affiliation":[{"name":"Catalysis and Inorganic Chemistry Division CSIR-National Chemical Laboratory  Dr. Homi Bhabha Road Pune 411 008 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sayana","family":"Mansuri","sequence":"additional","affiliation":[{"name":"Catalysis and Inorganic Chemistry Division CSIR-National Chemical Laboratory  Dr. Homi Bhabha Road Pune 411 008 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4525-3912","authenticated-orcid":false,"given":"Chinnakonda S.","family":"Gopinath","sequence":"additional","affiliation":[{"name":"Catalysis and Inorganic Chemistry Division CSIR-National Chemical Laboratory  Dr. Homi Bhabha Road Pune 411 008 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,2,8]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc51203g"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2gc16344f"},{"key":"e_1_2_8_3_1","unstructured":"\u00a0"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0200116"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm903368r"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60282f"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/bbb.1328"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA12442F"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym11081326"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA06847C"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2016.11.023"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs5006597"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201300949"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6RA11390G"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matlet.2015.04.030"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/slct.202004115"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(99)00316-8"},{"key":"e_1_2_8_18_1","volume-title":"Oxidation of Alcohols to Aldehydes and Ketones: AGuide to Current Common Practice, 1st","author":"Tojo G.","year":"2006"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/bs.adomc.2015.02.004"},{"key":"e_1_2_8_20_1","volume-title":"Fine chemicals through heterogeneous catalysis, 1st","author":"Sheldon R. 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