{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T15:16:43Z","timestamp":1759936603198,"version":"build-2065373602"},"reference-count":152,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2023,2,17]],"date-time":"2023-02-17T00:00:00Z","timestamp":1676592000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22103027"],"award-info":[{"award-number":["22103027"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2023,4,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Density functional theory calculations have been utilized to investigate the synergistic effect of palladium(0) and copper(I) catalyzed selective formation of allylated indole from (2\u2010alkynyl)\u2010phenylisocyanate and allyl methyl carbonate. The main competing reaction yielding the <jats:italic>N<\/jats:italic>\u2010allyl carbamate was also considered. Calculated results indicate that using the Pd(0)\u2010complex alone, the generation of indole is kinetically much less favored than producing the <jats:italic>N<\/jats:italic>\u2010allyl carbamate compound. However, the co\u2010addition of Cu(I) catalyst can considerably decrease the barrier for the intramolecular cyclization step, leading to the formation of the indole product. Analysis of the cyclization process suggests that Cu(I) complex can act as a Lewis acid to activate the linear alkyne group via a \u03c0\u2010coordination manner prior to the formation of a 5\u2010membered ring transition state toward indole formation. Altogether, the mechanistic insights revealed in the present study aim at a better understanding of the mechanism and the factors governing the selectivity in synergistic Pd\/Cu catalysis.<\/jats:p>","DOI":"10.1002\/asia.202201259","type":"journal-article","created":{"date-parts":[[2023,2,6]],"date-time":"2023-02-06T23:28:31Z","timestamp":1675726111000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Mechanistic Insights into the Synergistic Effect of Palladium(0) and Copper(I) on the Selective Transformation of Isocyanate to Indole"],"prefix":"10.1002","volume":"18","author":[{"given":"Cai\u2010Yun","family":"Ding","sequence":"first","affiliation":[{"name":"Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica Hubei Key Laboratory of Materials Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  Wuhan 430074 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Man","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica Hubei Key Laboratory of Materials Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  Wuhan 430074 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8989-6928","authenticated-orcid":false,"given":"Rong\u2010Zhen","family":"Liao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica Hubei Key Laboratory of Materials Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  Wuhan 430074 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2023,2,17]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar400270x"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201301500"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar500167f"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00144G"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00162"},{"key":"e_1_2_8_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00272A"},{"key":"e_1_2_8_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00192C"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00386"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500610p"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00534E"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2016.11.005"},{"key":"e_1_2_8_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7OB00413C"},{"key":"e_1_2_8_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00556"},{"key":"e_1_2_8_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00385"},{"key":"e_1_2_8_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00692"},{"key":"e_1_2_8_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00644"},{"key":"e_1_2_8_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00064B"},{"key":"e_1_2_8_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.201800314"},{"key":"e_1_2_8_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201710330"},{"key":"e_1_2_8_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201710330"},{"key":"e_1_2_8_21_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-018-0001-2"},{"key":"e_1_2_8_22_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aao4798"},{"key":"e_1_2_8_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00555"},{"key":"e_1_2_8_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201904214"},{"key":"e_1_2_8_24_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201904214"},{"key":"e_1_2_8_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00417"},{"key":"e_1_2_8_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202008437"},{"key":"e_1_2_8_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202008437"},{"key":"e_1_2_8_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00462"},{"key":"e_1_2_8_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00198"},{"key":"e_1_2_8_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00153"},{"key":"e_1_2_8_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c01115"},{"key":"e_1_2_8_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00160"},{"key":"e_1_2_8_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c11408"},{"key":"e_1_2_8_33_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2021.11.015"},{"key":"e_1_2_8_34_1","unstructured":"\u00a0"},{"key":"e_1_2_8_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar200188f"},{"key":"e_1_2_8_36_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35333D"},{"key":"e_1_2_8_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar4001789"},{"key":"e_1_2_8_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500425u"},{"key":"e_1_2_8_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00134"},{"key":"e_1_2_8_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00043"},{"key":"e_1_2_8_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00092"},{"key":"e_1_2_8_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00334"},{"key":"e_1_2_8_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201603777"},{"key":"e_1_2_8_43_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201603777"},{"key":"e_1_2_8_44_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00895F"},{"key":"e_1_2_8_45_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00107F"},{"key":"e_1_2_8_46_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-017-0025"},{"key":"e_1_2_8_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00410"},{"key":"e_1_2_8_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00404"},{"key":"e_1_2_8_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00506"},{"key":"e_1_2_8_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00505"},{"key":"e_1_2_8_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201801575"},{"key":"e_1_2_8_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00567"},{"key":"e_1_2_8_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201808159"},{"key":"e_1_2_8_53_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201808159"},{"key":"e_1_2_8_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00559"},{"key":"e_1_2_8_55_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00736"},{"key":"e_1_2_8_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00329"},{"key":"e_1_2_8_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00348"},{"key":"e_1_2_8_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202104371"},{"key":"e_1_2_8_59_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00204"},{"key":"e_1_2_8_60_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00727K"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1039\/C1CS15219J"},{"key":"e_1_2_8_62_1","unstructured":"\u00a0"},{"key":"e_1_2_8_63_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050041j"},{"key":"e_1_2_8_64_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2sc00907b"},{"key":"e_1_2_8_65_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201102888"},{"key":"e_1_2_8_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201100752"},{"key":"e_1_2_8_67_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35258C"},{"key":"e_1_2_8_68_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35258C"},{"key":"e_1_2_8_69_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5OB00986C"},{"key":"e_1_2_8_70_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7OB02476B"},{"key":"e_1_2_8_71_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00787B"},{"key":"e_1_2_8_72_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC05556G"},{"key":"e_1_2_8_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00245"},{"key":"e_1_2_8_74_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202210086"},{"key":"e_1_2_8_75_1","unstructured":"\u00a0"},{"key":"e_1_2_8_76_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b01110"},{"key":"e_1_2_8_77_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b00187"},{"key":"e_1_2_8_78_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b12824"},{"key":"e_1_2_8_79_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b12174"},{"key":"e_1_2_8_80_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b04440"},{"key":"e_1_2_8_81_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c09148"},{"key":"e_1_2_8_82_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202111842"},{"key":"e_1_2_8_82_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202111842"},{"key":"e_1_2_8_83_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c01626"},{"key":"e_1_2_8_84_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c03711"},{"key":"e_1_2_8_85_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202212948"},{"key":"e_1_2_8_86_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC07271D"},{"key":"e_1_2_8_87_1","unstructured":"\u00a0"},{"key":"e_1_2_8_88_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b05460"},{"key":"e_1_2_8_89_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b01833"},{"key":"e_1_2_8_90_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702113"},{"key":"e_1_2_8_90_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201702113"},{"key":"e_1_2_8_91_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201707019"},{"key":"e_1_2_8_91_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201707019"},{"key":"e_1_2_8_92_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC00562H"},{"key":"e_1_2_8_93_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC08732B"},{"key":"e_1_2_8_94_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b02902"},{"key":"e_1_2_8_95_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c02150"},{"key":"e_1_2_8_96_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.6077"},{"key":"e_1_2_8_97_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c05087"},{"key":"e_1_2_8_98_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0OB02499F"},{"key":"e_1_2_8_99_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202208411"},{"key":"e_1_2_8_100_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-30152-7"},{"key":"e_1_2_8_101_2","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.021.202101044"},{"key":"e_1_2_8_102_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020902)41:17<3230::AID-ANIE3230>3.0.CO;2-W"},{"key":"e_1_2_8_102_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020902)114:17<3364::AID-ANGE3364>3.0.CO;2-Z"},{"key":"e_1_2_8_103_1","unstructured":"\u00a0"},{"key":"e_1_2_8_104_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs500905r"},{"key":"e_1_2_8_105_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs501688y"},{"key":"e_1_2_8_106_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b01931"},{"key":"e_1_2_8_107_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b00230"},{"key":"e_1_2_8_108_2","first-page":"9612","volume":"142","author":"Changotra A.","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_8_109_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c02270"},{"key":"e_1_2_8_110_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c12664"},{"key":"e_1_2_8_111_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c00016"},{"key":"e_1_2_8_112_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c07376"},{"key":"e_1_2_8_113_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c06243"},{"key":"e_1_2_8_114_1","unstructured":"\u00a0"},{"key":"e_1_2_8_115_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-012-4672-0"},{"key":"e_1_2_8_116_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201201026"},{"key":"e_1_2_8_117_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201201425"},{"key":"e_1_2_8_118_1","unstructured":"\u00a0"},{"key":"e_1_2_8_119_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(94)80224-6"},{"key":"e_1_2_8_120_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0471525"},{"key":"e_1_2_8_121_2","doi-asserted-by":"publisher","DOI":"10.1021\/om700669v"},{"key":"e_1_2_8_122_2","doi-asserted-by":"publisher","DOI":"10.1039\/b706926j"},{"key":"e_1_2_8_123_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201502368"},{"key":"e_1_2_8_123_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201502368"},{"key":"e_1_2_8_124_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.5b00523"},{"key":"e_1_2_8_125_2","doi-asserted-by":"publisher","DOI":"10.3762\/bjoc.14.148"},{"key":"e_1_2_8_126_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.8b00565"},{"key":"e_1_2_8_127_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b01477"},{"key":"e_1_2_8_128_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0RA07498E"},{"key":"e_1_2_8_129_2","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.202100751"},{"volume-title":"Gaussian 16","author":"Frisch M. J.","key":"e_1_2_8_130_1"},{"key":"e_1_2_8_131_1","unstructured":"\u00a0"},{"key":"e_1_2_8_132_2","first-page":"1029","volume":"4","author":"Roy L. E.","year":"2008","journal-title":"J. Comput. Chem."},{"key":"e_1_2_8_133_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF01114537"},{"key":"e_1_2_8_134_1","unstructured":"\u00a0"},{"key":"e_1_2_8_135_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF00749589"},{"key":"e_1_2_8_136_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF00748404"},{"key":"e_1_2_8_137_1","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"},{"key":"e_1_2_8_138_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp810292n"},{"key":"e_1_2_8_139_1","unstructured":"\u00a0"},{"key":"e_1_2_8_140_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.2370993"},{"key":"e_1_2_8_141_2","doi-asserted-by":"publisher","DOI":"10.1007\/s00214-007-0310-x"},{"key":"e_1_2_8_142_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.3382344"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202201259","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.202201259","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202201259","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T14:39:31Z","timestamp":1759934371000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202201259"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,2,17]]},"references-count":152,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2023,4,3]]}},"alternative-id":["10.1002\/asia.202201259"],"URL":"https:\/\/doi.org\/10.1002\/asia.202201259","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"type":"print","value":"1861-4728"},{"type":"electronic","value":"1861-471X"}],"subject":[],"published":{"date-parts":[[2023,2,17]]},"assertion":[{"value":"2022-12-17","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-02-17","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202201259"}}