{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T04:11:12Z","timestamp":1790223072179,"version":"4.1.0"},"reference-count":62,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2023,2,3]],"date-time":"2023-02-03T00:00:00Z","timestamp":1675382400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2023,4,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The cycloaddition reaction of\n                    <jats:italic>o<\/jats:italic>\n                    \u2010diisocyanoarenes with interelement compounds under light is a very important reaction system to clarify whether this reaction proceeds by radical cyclization or by aza\u2010Bergman cyclization. In this study, a series of diphosphines with phosphorus\u2010phosphorus single bonds were selected as interelement compounds, and their cycloaddition reactions with\n                    <jats:italic>o<\/jats:italic>\n                    \u2010diisocyanoarenes under light were investigated in detail to achieve a novel photoinduced synthesis of bisphosphinated quinoxalines via the radical cyclization pathway. In addition, the photoinduced reaction of diphosphines with isocyanides having\n                    <jats:italic>o<\/jats:italic>\n                    \u2010functional groups such as cyano and ethenyl groups allowed us to elucidate the reaction pathway and product selectivity of this bisphosphination. Furthermore, the one\u2010pot synthesis of Pd\n                    <jats:sup>II<\/jats:sup>\n                    \u2010quinoxaline complex was successfully achieved by applying the developed reaction.\n                  <\/jats:p>","DOI":"10.1002\/asia.202201269","type":"journal-article","created":{"date-parts":[[2023,1,29]],"date-time":"2023-01-29T22:29:29Z","timestamp":1675031369000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Photoinduced Synthesis of Bisphosphinated Quinoxalines via Radical Cyclization of\n                    <i>o<\/i>\n                    \u2010Diisocyanoarenes with Diphosphines"],"prefix":"10.1002","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1166-7559","authenticated-orcid":false,"given":"Yuki","family":"Yamamoto","sequence":"first","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Osaka Prefecture University  1-1 Gakuen-cho, Nakaku Sakai Osaka 599-8531 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8543-2560","authenticated-orcid":false,"given":"Akiya","family":"Ogawa","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Osaka Prefecture University  1-1 Gakuen-cho, Nakaku Sakai Osaka 599-8531 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,2,3]]},"reference":[{"key":"e_1_2_8_1_1","first-page":"392","volume":"06","author":"Ogawa A.","year":"2014","journal-title":"Comprehensive Organic Synthesis 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J. Org. Chem."},{"key":"e_1_2_8_53_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c02745"},{"key":"e_1_2_8_54_1","unstructured":"\u00a0"},{"key":"e_1_2_8_55_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2011.01.019"},{"key":"e_1_2_8_56_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2011.01.015"},{"key":"e_1_2_8_57_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2012.08.089"},{"key":"e_1_2_8_58_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT02612C"},{"key":"e_1_2_8_59_1","unstructured":"In our previous work on the radical addition of diphosphine monosulfide R2P(S)\u2212PR2to unsaturated compounds (ref. 12c) the use of various diphosphines bearingo-tolyl p-tolyl 2-furanyl and alkyl groups were tolerable and furthermore the use of unsymmetrical diphosphines such as Cy2P(S)\u2212PPh2successfully led to the formation of the corresponding adducts. In addition under the radical reaction conditions the radical species R2P\u22c5 can be generated from diphosphines R2P\u2212PR2bearing different functional groups. Therefore the method developed in this study has the potential to use diphosphine derivatives with various substituents as phosphorus sources."}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202201269","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.202201269","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202201269","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T15:53:39Z","timestamp":1759938819000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202201269"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,2,3]]},"references-count":62,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2023,4,17]]}},"alternative-id":["10.1002\/asia.202201269"],"URL":"https:\/\/doi.org\/10.1002\/asia.202201269","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,2,3]]},"assertion":[{"value":"2022-12-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-02-03","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202201269"}}