{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,29]],"date-time":"2026-06-29T23:09:15Z","timestamp":1782774555602,"version":"3.54.5"},"reference-count":70,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2023,3,9]],"date-time":"2023-03-09T00:00:00Z","timestamp":1678320000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2023,4,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>We have synthesized a small library of blue\u2010to\u2010green emissive single benzene\u2010based fluorophores (SBFs) in a short synthetic sequence. The molecules exhibit good Stokes shift in the range of 60\u2013110\u2005nm and select examples also possess very high fluorescence quantum yields of up to 87%. Theoretical investigations into the ground state and excited state geometries of many of these compounds reveal that good degree of planarization between the electron donor secondary amines and electron accepting benzodinitrile units can be achieved under certain solvatochromic conditions, giving rise to the strongly fluorescent behavior. On the other hand, the excited state geometry which lacks co\u2010planarity of the donor amine and the single benzene moiety can open up a non\u2010fluorescent channel. Additionally, in molecules with a dinitrobenzene acceptor, the perpendicular nitro moieties render the molecules completely non\u2010emissive.<\/jats:p>","DOI":"10.1002\/asia.202201314","type":"journal-article","created":{"date-parts":[[2023,2,27]],"date-time":"2023-02-27T12:35:44Z","timestamp":1677501344000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Amino\u2010Terephthalonitrile\u2010Based Single Benzene Fluorophores with Large Stokes Shifts and Solvatochromic Behavior"],"prefix":"10.1002","volume":"18","author":[{"given":"Tanya","family":"Raghava","sequence":"first","affiliation":[{"name":"Department of Chemistry BITS Pilani K.K. Birla Goa Campus  NH 17B, Bypass Road Zuarinagar Goa 403726 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anjan","family":"Chattopadhyay","sequence":"additional","affiliation":[{"name":"Department of Chemistry BITS Pilani K.K. Birla Goa Campus  NH 17B, Bypass Road Zuarinagar Goa 403726 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Purushothaman","family":"Bhavana","sequence":"additional","affiliation":[{"name":"Department of Chemistry BITS Pilani K.K. Birla Goa Campus  NH 17B, Bypass Road Zuarinagar Goa 403726 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6992-3928","authenticated-orcid":false,"given":"Subhadeep","family":"Banerjee","sequence":"additional","affiliation":[{"name":"Department of Chemistry BITS Pilani K.K. Birla Goa Campus  NH 17B, Bypass Road Zuarinagar Goa 403726 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,3,9]]},"reference":[{"key":"e_1_2_9_1_1","unstructured":"\u00a0"},{"key":"e_1_2_9_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm049679m"},{"key":"e_1_2_9_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35313J"},{"key":"e_1_2_9_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6TC03359H"},{"key":"e_1_2_9_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00030G"},{"key":"e_1_2_9_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ob42554a"},{"key":"e_1_2_9_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8RA02297F"},{"key":"e_1_2_9_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00719H"},{"key":"e_1_2_9_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0OB00515K"},{"key":"e_1_2_9_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00145"},{"key":"e_1_2_9_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/b802497a"},{"key":"e_1_2_9_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.200900727"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr990322p"},{"key":"e_1_2_9_14_1","unstructured":"\u00a0"},{"key":"e_1_2_9_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr5004425"},{"key":"e_1_2_9_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b03924"},{"key":"e_1_2_9_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b04404"},{"key":"e_1_2_9_18_1","unstructured":"\u00a0"},{"key":"e_1_2_9_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jchemed.5b00483"},{"key":"e_1_2_9_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15113d"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1088\/2050-6120\/ab7365"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0OB02387F"},{"key":"e_1_2_9_23_1","unstructured":"\u00a0"},{"key":"e_1_2_9_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.8b01251"},{"key":"e_1_2_9_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/adom.201900927"},{"key":"e_1_2_9_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201706517"},{"key":"e_1_2_9_27_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC00718A"},{"key":"e_1_2_9_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.201900405"},{"key":"e_1_2_9_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1CE01285A"},{"key":"e_1_2_9_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2021.110013"},{"key":"e_1_2_9_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.0c09106"},{"key":"e_1_2_9_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.9b00196"},{"key":"e_1_2_9_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201904478"},{"key":"e_1_2_9_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201706517"},{"key":"e_1_2_9_34_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201706517"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.188601901105"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200803432"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2011.05.087"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201502365"},{"key":"e_1_2_9_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201502365"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC06260B"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b08524"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/slct.202001999"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmcl.2015.01.006"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2OB00442A"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/ci0497051"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jlumin.2011.05.048"},{"key":"e_1_2_9_46_1","unstructured":"\u00a0"},{"key":"e_1_2_9_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp000156l"},{"key":"e_1_2_9_48_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1394921"},{"key":"e_1_2_9_49_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.471140"},{"key":"e_1_2_9_50_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(96)00440-X"},{"key":"e_1_2_9_51_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(96)01343-7"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.10189"},{"key":"e_1_2_9_53_1","unstructured":"\u00a0"},{"key":"e_1_2_9_54_2","first-page":"11","author":"Chen Meng-Chi","journal-title":"ChemPlusChem.(86)"},{"key":"e_1_2_9_55_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp310770s"},{"key":"e_1_2_9_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp209271u"},{"key":"e_1_2_9_57_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(00)00432-2"},{"key":"e_1_2_9_58_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp001690w"},{"key":"e_1_2_9_59_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp2005524"},{"key":"e_1_2_9_60_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CP01232A"},{"key":"e_1_2_9_61_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201705854"},{"key":"e_1_2_9_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201704162"},{"key":"e_1_2_9_62_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201704162"},{"key":"e_1_2_9_63_1","unstructured":"\u00a0"},{"key":"e_1_2_9_64_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.214070"},{"key":"e_1_2_9_65_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2015.03.064"},{"key":"e_1_2_9_66_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2016.08.064"},{"key":"e_1_2_9_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochemrev.2019.100338"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202201314","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.202201314","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202201314","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T15:53:34Z","timestamp":1759938814000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202201314"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,3,9]]},"references-count":70,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2023,4,17]]}},"alternative-id":["10.1002\/asia.202201314"],"URL":"https:\/\/doi.org\/10.1002\/asia.202201314","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,3,9]]},"assertion":[{"value":"2023-01-02","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-03-09","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202201314"}}