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The protocol accommodates several bioactive molecules and allows downstream synthetic manipulations leading to a 2,3\u2010benzodiazepine scaffold. The reaction features a reversible metalation step and favors a regioselective \u03b2\u2010hydride elimination event.<\/jats:p>","DOI":"10.1002\/asia.202300243","type":"journal-article","created":{"date-parts":[[2023,4,15]],"date-time":"2023-04-15T02:35:06Z","timestamp":1681526106000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Ru(II)\u2010Catalyzed Oxidative Cross\u2010Dehydrogenative Alkenylations of Aromatic Amides and Ketones with Unactivated Olefins"],"prefix":"10.1002","volume":"18","author":[{"given":"Chandan Kumar","family":"Giri","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Madras  Chennai 600036 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sudeshna","family":"Mondal","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Madras  Chennai 600036 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9415-7137","authenticated-orcid":false,"given":"Mahiuddin","family":"Baidya","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Madras  Chennai 600036 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,4,25]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/42190"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr000013v"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpba.2010.01.004"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2011.09.030"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmcl.2014.09.074"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmcl.2014.04.105"},{"key":"e_1_2_3_8_1","unstructured":"\u00a0"},{"key":"e_1_2_3_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9903048"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr020039h"},{"key":"e_1_2_3_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.202100071"},{"key":"e_1_2_3_12_1","unstructured":"For"},{"key":"e_1_2_3_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)90648-8"},{"key":"e_1_2_3_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)99121-X"},{"key":"e_1_2_3_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01053a047"},{"key":"e_1_2_3_16_1","unstructured":"Selective reviews on Ru-catalyzed C\u2212H olefination:"},{"key":"e_1_2_3_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr300153j"},{"key":"e_1_2_3_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2SC21524A"},{"key":"e_1_2_3_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7QO00134G"},{"key":"e_1_2_3_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.202001159"},{"key":"e_1_2_3_21_1","unstructured":"For general reviews on CDC reactions:"},{"key":"e_1_2_3_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar800164n"},{"key":"e_1_2_3_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200902996"},{"key":"e_1_2_3_23_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200902996"},{"key":"e_1_2_3_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.200900487"},{"key":"e_1_2_3_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304268"},{"key":"e_1_2_3_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201304268"},{"key":"e_1_2_3_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.9b01704"},{"key":"e_1_2_3_27_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1GC01871J"},{"key":"e_1_2_3_28_1","unstructured":"For Selective reports on Ru(II)-catalyzed C\u2212H olefination with activated olefins:"},{"key":"e_1_2_3_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol201563r"},{"key":"e_1_2_3_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol2032575"},{"key":"e_1_2_3_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/om3008162"},{"key":"e_1_2_3_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo5008465"},{"key":"e_1_2_3_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b01370"},{"key":"e_1_2_3_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201507801"},{"key":"e_1_2_3_34_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201507801"},{"key":"e_1_2_3_35_1","unstructured":"For weak coordination assisted Ru(II)-catalyzed C\u2212H olefination with unactivated olefins see:"},{"key":"e_1_2_3_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.1c02424"},{"key":"e_1_2_3_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.2c04036"},{"key":"e_1_2_3_38_2","first-page":"373","volume":"358","author":"Xiao Xue J. 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