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Herein, a series of SnMnO<jats:sub>x<\/jats:sub> catalysts for the catalytic combustion of CVOCs were prepared by the changing of Sn\u2010doping way to regulate the electron valance state of Mn element, including reflux (R\u2010SnMnO<jats:sub>x<\/jats:sub>), co\u2010precipitation (C\u2010SnMnO<jats:sub>x<\/jats:sub>) and impregnation (I\u2010SnMnO<jats:sub>x<\/jats:sub>). It was discovered that the R\u2010SnMnO<jats:sub>x<\/jats:sub> catalyst had better activity and chlorine resistance than the R\u2010MnO<jats:sub>x<\/jats:sub>, C\u2010SnMnO<jats:sub>x<\/jats:sub> and I\u2010SnMnO<jats:sub>x<\/jats:sub> catalyst, and we discovered that the doping ways of Sn in MnO<jats:sub>x<\/jats:sub> catalyst could regulate greatly the surface acidity, active oxygen species, the chemical state of Mn<jats:sup>n+<\/jats:sup> species, and redox ability. Especially, the R\u2010SnMnO<jats:sub>x<\/jats:sub> catalysts exhibit excellent water resistance, and the reasons were related to the strong interaction of Sn<jats:sup>n+<\/jats:sup> and Mn<jats:sup>n+<\/jats:sup>, which could promote obviously the dispersion of active Mn species, form a large number of acid sites, provide the abundant lattice oxygen species, and own the excellent redox ability, which accelerate the rate of charge transfer between Sn<jats:sup>n+<\/jats:sup> and Mn<jats:sup>n+<\/jats:sup> (Sn<jats:sup>4+<\/jats:sup>+Mn<jats:sup>2+<\/jats:sup>\u2192Sn<jats:sup>2+<\/jats:sup>+Mn<jats:sup>4+<\/jats:sup>) to produce the abundant active species and accelerate the rapid conversion of benzene and intermediates conversion.<\/jats:p>","DOI":"10.1002\/asia.202300413","type":"journal-article","created":{"date-parts":[[2023,6,26]],"date-time":"2023-06-26T10:05:02Z","timestamp":1687773902000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Insights into the Electronic Structure Effect of SnMnO<sub>x<\/sub> Nanorod Catalysts for Low\u2010Temperature Catalytic Combustion of o\u2010Dichlorobenzene"],"prefix":"10.1002","volume":"18","author":[{"given":"Jie","family":"Wang","sequence":"first","affiliation":[{"name":"School of Petroleum and Chemical Lanzhou University of Technology  Lanzhou 730050 P. 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