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The desired penta\u2010substituted pyrrolidine products were obtained in high yields and in moderate to good enantio\u2010 and diastereoselectivities. Also, an isomerization reaction in silica gel was performed for the formation of another diastereomer in high yields with retention of enantioselectivities.<\/jats:p>","DOI":"10.1002\/asia.202300563","type":"journal-article","created":{"date-parts":[[2023,8,14]],"date-time":"2023-08-14T10:59:53Z","timestamp":1692010793000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Organocatalytic Asymmetric Domino [3+2]\u2010Cycloaddition\u2010Acyl Transfer Reaction between Azomethine Ylides and <i>\u03b1<\/i>\u2010Nitro\u2010<i>\u03b1<\/i>,<i>\u03b2<\/i>\u2010Unsaturated Ketones"],"prefix":"10.1002","volume":"18","author":[{"given":"Subas Chandra","family":"Sahoo","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Guwahati  North Guwahati Assam India 781039"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chandrakanta","family":"Parida","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Guwahati  North Guwahati Assam India 781039"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7581-1831","authenticated-orcid":false,"given":"Subhas Chandra","family":"Pan","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Guwahati  North Guwahati Assam India 781039"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,8,28]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.287.5460.1964"},{"key":"e_1_2_6_3_2","unstructured":"J.\u2005J. 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