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Herein, we report a simple and easy\u2010to\u2010use protocol for the twin application of TiO(acac)<jats:sub>2<\/jats:sub>, as a reagent and an activator to synthesize \u03b2\u2010enamino ketones with amines in acetonitrile. The same early transition metal precursor when employed in N,N\u2010dimethylformamide with the amines, resulted in the formation of the substituted amides. Both reactions were explored with various substrates to check the viability of the present protocol. 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