{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,15]],"date-time":"2026-04-15T06:10:12Z","timestamp":1776233412753,"version":"3.50.1"},"reference-count":52,"publisher":"Wiley","issue":"23","license":[{"start":{"date-parts":[[2023,11,9]],"date-time":"2023-11-09T00:00:00Z","timestamp":1699488000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2023,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Herein, for the first time we have explored the umpolung reactivity of the vinylogous carbon center of diazo arylidene succinimide (DAS) through rhodium catalysis to achieve [2,3]\u2010Stevens rearrangement of \u03b1\u2010thioether esters. The protocol has successfully demonstrated the distal C\u2212H bond functionalization of the\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010thioether esters. Alongside, the carbenoid reactivity of DAS has also been achieved with Doyle\u2010Kirmse reaction of allyl\/propargyl phenyl sulfides. The protocol proved to be practical to synthesize a wide variety of [2,3]\u2010Stevens rearrangement products exclusively and the possible side products emanating from Pummerer rearrangement and [1,2]\u2010Stevens rearrangement were not observed. This catalytic protocol works smoothly in environmentally benign solvent under open air to afford the corresponding desired products with excellent diastereo\u2010, regio\u2010 and chemo\u2010selectivities in good to excellent yields. The protocol also proved to be scalable on gram quantity.\n                  <\/jats:p>","DOI":"10.1002\/asia.202300774","type":"journal-article","created":{"date-parts":[[2023,10,13]],"date-time":"2023-10-13T02:55:05Z","timestamp":1697165705000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Umpolung Reactivity of Diazo Arylidene Succinimides: Distal C\u2212H Functionalization of\n                    <i>\u03b1<\/i>\n                    \u2010Thiocarbonyls from the Reactive Carbenoid Center"],"prefix":"10.1002","volume":"18","author":[{"given":"Onkar S.","family":"Bankar","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Science Education and Research (IISER) Pune  Dr. Homi Bhabha Road, NCL Colony, Pashan Pune Maharashtra 411008 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Debasish","family":"Laha","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Science Education and Research (IISER) Pune  Dr. Homi Bhabha Road, NCL Colony, Pashan Pune Maharashtra 411008 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kajal B.","family":"Meher","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Science Education and Research (IISER) Pune  Dr. Homi Bhabha Road, NCL Colony, Pashan Pune Maharashtra 411008 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7739-9553","authenticated-orcid":false,"given":"Ramakrishna G.","family":"Bhat","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Science Education and Research (IISER) Pune  Dr. Homi Bhabha Road, NCL Colony, Pashan Pune Maharashtra 411008 India"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2023,11,9]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00890a018"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.197902393"},{"key":"e_1_2_8_3_1","first-page":"1133","volume-title":"Organic Chemistry","author":"Clayden J.","year":"2001"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00629"},{"key":"e_1_2_8_5_1","unstructured":"\u00a0"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja503163k"},{"key":"e_1_2_8_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo5023102"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201203217"},{"key":"e_1_2_8_9_1","unstructured":"\u00a0"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/9781118730379.ch13"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00324B"},{"key":"e_1_2_8_12_1","unstructured":"\u00a0"},{"key":"e_1_2_8_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.1c01381"},{"key":"e_1_2_8_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201506764"},{"key":"e_1_2_8_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC04106J"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.202000123"},{"key":"e_1_2_8_17_1","unstructured":"\u00a0"},{"key":"e_1_2_8_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.1c01710"},{"key":"e_1_2_8_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.202200062"},{"key":"e_1_2_8_20_1","unstructured":"\u00a0"},{"key":"e_1_2_8_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol9028385"},{"key":"e_1_2_8_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202004328"},{"key":"e_1_2_8_23_1","unstructured":"\u00a0"},{"key":"e_1_2_8_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(98)01510-X"},{"key":"e_1_2_8_25_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0040-1706556"},{"key":"e_1_2_8_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.0c02356"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1OB00773D"},{"key":"e_1_2_8_28_1","unstructured":"\u00a0"},{"key":"e_1_2_8_29_2","first-page":"93","volume":"65","author":"Khlebnikov A. 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