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In recent years, the detection of explosives has attracted increasing attention due to security and counterterrorism issues. Herein, two diphenyl\u2212anthracene (DPA) derivatives were designed and synthesized by introducing strong electron withdrawing fluorine atoms and cyano\u2010groups to DPA, which exhibited strong fluorescence both in the solution and solid phase with the absolute quantum yields up to 70.4\u2009% and 45.9\u2009% respectively. The detection behavior of nitroaromatic explosives such as picric acid (PA), 2,4,6\u2010trinitrotoluene (TNT) and 3\u2010Nitropropionic acid (3\u2010NP) also shows good sensitivity with the quenching constant as high as 6.3\u00d710<jats:sup>4<\/jats:sup>\u2005L\u2009mol<jats:sup>\u22121<\/jats:sup>. Theoretical calculation demonstrates that the fluorescence quenching behavior of the two DPA derivatives is caused by the behavior of photoinduced electron transfer (PET) and the resonance energy transfer (RET) studies explained the higher sensitivity and selectivity of both compounds towards PA than other nitro\u2010containing explosives. Furthermore, the strong solid\u2010state fluorescence of the DPA derivatives also shows excellent advantages in enhancing latent fingerprint recognition.<\/jats:p>","DOI":"10.1002\/asia.202300775","type":"journal-article","created":{"date-parts":[[2023,12,7]],"date-time":"2023-12-07T21:12:29Z","timestamp":1701983549000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis of High\u2010Fluorescent Diphenyl\u2212anthracene Derivatives and Application in Detection of Nitroaromatic Explosives and Fingerprint Identification"],"prefix":"10.1002","volume":"19","author":[{"given":"Jiagen","family":"Lai","sequence":"first","affiliation":[{"name":"College of Material Chemistry and Chemical Engineering Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education Key Laboratory of Organosilicon Material Technology of Zhejiang Province Hangzhou Normal University  Hangzhou 311121 Zhejiang P. R. 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