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Bis\u2010BF<jats:sub>2<\/jats:sub> complex was converted to bis\u2010Pd<jats:sup>II<\/jats:sup> complex via its free base. Macrocycles bis\u2010BF<jats:sub>2<\/jats:sub> and tris\u2010BF<jats:sub>2<\/jats:sub> complex take M\u00f6bius topology but are nonaromatic, since the macrocyclic conjugation is disrupted by the locally aromatic 1,4\u2010phenylene units. In contrast, bis\u2010Pd<jats:sup>II<\/jats:sup> complex is a weakly H\u00fcckel 38\u03c0\u2010aromatic macrocycle as evinced by its red\u2010shifted, enhanced, and structured Q\u2010like bands and a small electrochemical HOMO\u2010LUMO gap. Interestingly, one 1,4\u2010pheylene part of bis\u2010Pd<jats:sup>II<\/jats:sup> complex takes a quinonoidal distorted structure and the other takes a usual benzene structure in a figure\u2010eight conformation with H\u00fcckel topology.<\/jats:p>","DOI":"10.1002\/asia.202300923","type":"journal-article","created":{"date-parts":[[2023,11,21]],"date-time":"2023-11-21T08:48:42Z","timestamp":1700556522000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Di(<i>p\u2010<\/i>dibenzi)[40]decaphyrin(1.0.0.0.0.1.0.0.0.0) Pd<sup>II<\/sup> Complex: A Weakly H\u00fcckel 38\u03c0\u2010Aromatic Macrocycle"],"prefix":"10.1002","volume":"19","author":[{"given":"Chengwei","family":"Wang","sequence":"first","affiliation":[{"name":"Key Laboratory of Chemical Biology and Traditional Chinese Medicine Ministry of Educational of China Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province College 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