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The structure contains layers of tetrahedral ions (Zn<jats:sup>2+<\/jats:sup>\/Ga<jats:sup>3+<\/jats:sup>) connected by octahedrally coordinated In<jats:sup>3+<\/jats:sup> ion forming the three\u2010dimensional structure with voids where the Ba<jats:sup>2+<\/jats:sup> ions occupy. The TM substituted compounds form with new colors. The origin of the color was understood based on the ligand\u2010field transitions. The near IR reflectivity studies indicate that the Ni \u2013 substituted compounds exhibit good near \u2013 IR reflectivity behavior, making them possible candidates for \u2018cool pigments\u2019. The temperature dependent dielectric studies indicate that the InBaZn<jats:sub>3<\/jats:sub>GaO<jats:sub>7<\/jats:sub> compound undergoes a phase transition at ~360\u2009\u00b0C. The compounds are active towards second harmonic generation (SHG). Magnetic studies show the compounds, InBaZn<jats:sub>2<\/jats:sub>CoFeO<jats:sub>7<\/jats:sub> and InBaZn<jats:sub>2<\/jats:sub>CuFeO<jats:sub>7<\/jats:sub> to be anti\u2010ferromagnetic in nature. The copper containing compounds were found to be good catalysts, under visible light, for the oxidation of aromatic alkenes. The many properties observed in the swedenborgite structure\u2010based compounds suggests that the mineral structure offers a fertile ground to investigate newer compounds and properties.<\/jats:p>","DOI":"10.1002\/asia.202301113","type":"journal-article","created":{"date-parts":[[2024,2,7]],"date-time":"2024-02-07T05:02:01Z","timestamp":1707282121000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis, Optical, Dielectric, SHG, Magnetic and Visible Light Driven Catalytic Studies on Compounds Belonging to the Swedenborgite Structure"],"prefix":"10.1002","volume":"19","author":[{"given":"Sivakumar","family":"Gurusamy","sequence":"first","affiliation":[{"name":"Solid State and Structural Chemistry Unit Indian Institute of Science  Bangalore 560012 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Souvik","family":"Banerjee","sequence":"additional","affiliation":[{"name":"Chemistry and Physics of Materials Unit Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR) Jakkur P.O.  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