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Conversions of the stannylene with P<jats:sub>4<\/jats:sub> gave a non\u2010pyrophoric, air\u2010stable storage compound, which releases P<jats:sub>4<\/jats:sub> quantitively upon irradiation with light (354 or 455\u2005nm). Alternatively, the phosphorus cage is detached by reacting the storage compound with PhChChPh (Ch=Se, Te). Despite the recent advances in the directed conversion of P<jats:sub>4<\/jats:sub> using main group element compounds, Ar*<jats:sub>2<\/jats:sub>Sn constitutes only the second structurally characterized example of a stannylene capable of performing controlled, reversible addition and release of white phosphorus.<\/jats:p>","DOI":"10.1002\/asia.202400168","type":"journal-article","created":{"date-parts":[[2024,4,5]],"date-time":"2024-04-05T12:05:27Z","timestamp":1712318727000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["An Air\u2010Stable Storage Compound for White Phosphorus: Reversible Addition to a Stannylene and Chemical Release of P<sub>4<\/sub>"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6014-9788","authenticated-orcid":false,"given":"Beate G.","family":"Steller","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry Graz University of Technology  Stremayrgasse 9\/V 8010 Graz Austria"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-8520-7121","authenticated-orcid":false,"given":"Clara A.","family":"Roller","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Graz University of Technology  Stremayrgasse 9\/V 8010 Graz Austria"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2799-1479","authenticated-orcid":false,"given":"Michaela","family":"Flock","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Graz University of Technology  Stremayrgasse 9\/V 8010 Graz Austria"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9523-5010","authenticated-orcid":false,"given":"Roland C.","family":"Fischer","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Graz University of Technology  Stremayrgasse 9\/V 8010 Graz Austria"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2024,5,7]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C39740000895"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/c39760000261"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/b820835b"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/DT9800002428"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00001a054"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)00313-1"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr900093s"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja053247a"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1176443"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812675"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b00710"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402031"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013423"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201702067"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.0c00332"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr900349u"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/b510917e"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC01192G"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200701203"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-020-0518-0"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT01522A"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC06223F"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SC06430A"},{"journal-title":"Eur. 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