{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,5]],"date-time":"2026-05-05T10:36:53Z","timestamp":1777977413799,"version":"3.51.4"},"reference-count":67,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2024,5,6]],"date-time":"2024-05-06T00:00:00Z","timestamp":1714953600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21772186"],"award-info":[{"award-number":["21772186"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2024,6,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>N,N,P\u2010Pincer nickel complexes effectively catalyze reaction of alcohols with benzylphosphine oxides to form alkenes in good yields. The protocol suits for a wide scope of substrates and generates only <jats:italic>E<\/jats:italic>\u2010configurated alkenes. The method also shows good compatibility of functional groups. Methoxy, methylthio, trifluoromethyl, ketal, fluoro, chloro, bromo, thienyl, and furyl groups are tolerated. The mechanism studies support that the reaction proceeds through catalytic dehydrogenation of alcohols to aldehydes or ketones followed by condensation with benzyldiphenylphosphine oxides in the presence of KO<jats:italic>t<\/jats:italic>Bu.<\/jats:p>","DOI":"10.1002\/asia.202400255","type":"journal-article","created":{"date-parts":[[2024,4,10]],"date-time":"2024-04-10T22:04:52Z","timestamp":1712786692000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Pincer Nickel\u2010Catalyzed Olefination of Alcohols with Benzylphosphine Oxides"],"prefix":"10.1002","volume":"19","author":[{"given":"Yu\u2010Tong","family":"Duan","sequence":"first","affiliation":[{"name":"CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry University of Science and Technology of China  Hefei Anhui 230026"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bo","family":"Yang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry University of Science and Technology of China  Hefei Anhui 230026"},{"name":"Frontiers Science Center for Transformative Molecules (FSCTM) Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 P. R. China."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8126-8778","authenticated-orcid":false,"given":"Zhong\u2010Xia","family":"Wang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry University of Science and Technology of China  Hefei Anhui 230026"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2024,5,6]]},"reference":[{"key":"e_1_2_9_1_1","unstructured":"\u00a0"},{"key":"e_1_2_9_2_2","doi-asserted-by":"crossref","unstructured":"Modern Carbonyl Olefination(Ed. T. Takeda) Wiley-VCH Weinheim 2004;","DOI":"10.1016\/S1351-4180(04)00607-5"},{"key":"e_1_2_9_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/np9702998"},{"key":"e_1_2_9_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmcl.2010.03.018"},{"key":"e_1_2_9_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/srep00314"},{"key":"e_1_2_9_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804729"},{"key":"e_1_2_9_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19980302)37:4<402::AID-ANIE402>3.0.CO;2-9"},{"key":"e_1_2_9_8_1","unstructured":"\u00a0"},{"key":"e_1_2_9_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00094a007"},{"key":"e_1_2_9_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199602411"},{"key":"e_1_2_9_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr60287a005"},{"key":"e_1_2_9_12_2","doi-asserted-by":"publisher","DOI":"10.2174\/1385272819666150311231006"},{"key":"e_1_2_9_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo01266a061"},{"key":"e_1_2_9_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/a908402i"},{"key":"e_1_2_9_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/b208078h"},{"key":"e_1_2_9_16_2","doi-asserted-by":"publisher","DOI":"10.2174\/1570179420666230510104114"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2016.10.002"},{"key":"e_1_2_9_18_1","unstructured":"\u00a0"},{"key":"e_1_2_9_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2009.04.023"},{"key":"e_1_2_9_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200900951"},{"key":"e_1_2_9_21_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0029-1217333"},{"key":"e_1_2_9_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC02902C"},{"key":"e_1_2_9_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202001209"},{"key":"e_1_2_9_24_1","unstructured":"\u00a0"},{"key":"e_1_2_9_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.2c02050"},{"key":"e_1_2_9_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.2c03067"},{"key":"e_1_2_9_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.1c01553"},{"key":"e_1_2_9_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b04013"},{"key":"e_1_2_9_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b02811"},{"key":"e_1_2_9_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06993"},{"key":"e_1_2_9_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.1c00592"},{"key":"e_1_2_9_32_1","unstructured":"\u00a0"},{"key":"e_1_2_9_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.8b02911"},{"key":"e_1_2_9_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201407281"},{"key":"e_1_2_9_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201505109"},{"key":"e_1_2_9_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.9b00567"},{"key":"e_1_2_9_37_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC02603G"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.1c00685"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b01327"},{"key":"e_1_2_9_40_1","unstructured":"\u00a0"},{"key":"e_1_2_9_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804729"},{"key":"e_1_2_9_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201801573"},{"key":"e_1_2_9_43_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0037-1610313"},{"key":"e_1_2_9_44_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2020.130968"},{"key":"e_1_2_9_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.202000781"},{"key":"e_1_2_9_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202101455"},{"key":"e_1_2_9_47_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2CY01030E"},{"key":"e_1_2_9_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.6561"},{"key":"e_1_2_9_49_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC03591E"},{"key":"e_1_2_9_50_1","unstructured":"\u00a0"},{"key":"e_1_2_9_51_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.1c02132"},{"key":"e_1_2_9_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200290034"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200290034"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CY02060B"},{"key":"e_1_2_9_55_1","unstructured":"The catalytic dehydrogenative cross-coupling reaction between two alcohols can also occur to lead to \u03b2-alkylation species via transient \u03b1 \u03b2-unsaturated carbonyl compound with a new C\u2212C double bond. Selected refs."},{"key":"e_1_2_9_56_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9OB00418A"},{"key":"e_1_2_9_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.1c00782"},{"key":"e_1_2_9_58_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.1c00328"},{"key":"e_1_2_9_59_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT03593A"},{"key":"e_1_2_9_60_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202101077"},{"key":"e_1_2_9_61_1","unstructured":"\u00a0"},{"key":"e_1_2_9_62_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4OB01041H"},{"key":"e_1_2_9_63_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4QO00321G"},{"key":"e_1_2_9_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.5b02151"},{"key":"e_1_2_9_65_1","unstructured":"\u00a0"},{"key":"e_1_2_9_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.200690215"},{"key":"e_1_2_9_67_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806522"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202400255","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T17:18:00Z","timestamp":1759943880000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202400255"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,5,6]]},"references-count":67,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2024,6,3]]}},"alternative-id":["10.1002\/asia.202400255"],"URL":"https:\/\/doi.org\/10.1002\/asia.202400255","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,5,6]]},"assertion":[{"value":"2024-03-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-05-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202400255"}}