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This method offers a convenient and adaptable pathway for synthesizing these important molecular structures with potential for further advancements. By reacting benzyl azide derivatives with TfOH under the presence of water, this process generates iminium ion, formaldehyde, and aniline intermediates in\u2005situ. Notably, this conversion is reversible under acidic conditions, allowing for the regeneration of the iminium ion and ultimately leading to the formation of the desired Tr\u00f6ger's base product. 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