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Besides solution phase studies, ferrocene derivatives are well\u2010explored in molecular thin films, including self\u2010assembled monolayers on various electrodes for understanding on\u2010surface redox behavior, molecular electronics, and charge storage applications. Heterogeneous charge transfer is an imperative parameter for efficient charge transport in spin\u2010dependent electrochemistry, photoelectrochemistry, and molecular electronic devices. In this work, we aim to study the electrochemical charge transfer of ferrocene on various electrodes such as commercially obtained glassy carbon, graphite rod, indium tin oxide (ITO), and as\u2010prepared gold, and nickel to determine the impact of the nature of the working electrode on the electron transfer rate, diffusion coefficient, and reversibility of the redox process. Both the direct current and alternating current\u2010based electrochemical experiments are performed, followed by digitization of the experimental results. The kinetics of electron transfer and electrochemical reversibility reveal a strong dependence on the nature of the working electrode, as the electrochemically driven oxidation and reduction of the material of interest are directly related to the Fermi energy and electronic structure of the working electrode.<\/jats:p>","DOI":"10.1002\/asia.202400744","type":"journal-article","created":{"date-parts":[[2024,8,13]],"date-time":"2024-08-13T08:30:34Z","timestamp":1723537834000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Electrochemical Charge Transfer Kinetics of Ferrocene in the Light of Different Working Electrodes"],"prefix":"10.1002","volume":"19","author":[{"given":"Rajwinder","family":"Kaur","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kanpur  Uttar Pradesh 208 016 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abhik","family":"Ghoshal","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kanpur  Uttar Pradesh 208 016 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Prachi","family":"Galav","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kanpur  Uttar Pradesh 208 016 India"},{"name":"Department of Chemistry Janki Devi Bajaj Government Girls College  Kota, Rajasthan 324 001 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9415-5147","authenticated-orcid":false,"given":"Prakash Chandra","family":"Mondal","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kanpur  Uttar Pradesh 208 016 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,9,24]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05226"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b10538"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00446"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201706423"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5b00550"},{"key":"e_1_2_9_6_1","doi-asserted-by":"crossref","unstructured":"J.\u2005R. 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