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An anionic iron(III)porphyrin and a cationic manganese(III)porphyrin were immobilized on different ZnO solids predominantly by electrostatic interactions. In general, the prepared MP\u2010free ZnO solid yielded modest catalytic results which had apparently no direct correlation with their textural properties or morphology. On the other hand, when these ZnO solids had iron or manganese porphyrin sensitizing them, their catalytic performances changed and a superior yield towards H<jats:sub>2<\/jats:sub> production was observed in comparison to the pure ZnO solids, making evident the synergy achieved between these two components (ZnO and metalloporphyrins) for the prepared solids. It was also observed that the metalloporphyrins and the respective free\u2010base ligand suffered redox reactions when used as homogenous catalyst in this reaction, which could influence their performances as catalysts. The same was not observed in the solids containing immobilized MP, suggesting some protective effect of the ZnO solids on the MP complexes upon immobilization probably due to interaction of the complexes with the ZnO matrix.<\/jats:p>","DOI":"10.1002\/asia.202401011","type":"journal-article","created":{"date-parts":[[2024,10,4]],"date-time":"2024-10-04T03:11:04Z","timestamp":1728011464000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["ZnO with Different Morphologies Sensitized by Metalloporphyrins as Catalysts for H<sub>2<\/sub> Production by Water Splitting Under Sunlight"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3460-2467","authenticated-orcid":false,"given":"Jo\u00e3o F.","family":"Stival","sequence":"first","affiliation":[{"name":"Department of Chemistry Federal University of Paran\u00e1  Av. Coronel. 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