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This method exhibits precise specificity for the geminal substituted olefinic center and facilitates the synthesis of substituted phthalide and hydroisocoumarin derivatives. This method has been effectively applied for late\u2010state functionalization to produce bioactive natural products such as rumphellaone A, mycophenolate, and (\u2212)\u2010ambrox. The successful gram\u2010scale synthesis of the anticonvulsant, hypnotic drug (\u00b1)\u2010ethyl phenyl butyro lactone (EPBL), (\u00b1)\u2010Boivinianin A and the ability to synthesize challenging spiro and bicyclic lactone underscores the synthetic potential of this methodology. 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