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A uniform synthetic protocol yielded three structurally related series of general composition {Ln(solvent)<jats:sub>n<\/jats:sub>}[NaMo<jats:sub>8<\/jats:sub>O<jats:sub>26<\/jats:sub>]\u2009\u22c5\u2009yH<jats:sub>2<\/jats:sub>O, with the whole lanthanide series (except for radioactive Pm). The three series are (i) {Ln(DMSO)<jats:sub>8<\/jats:sub>}[NaMo<jats:sub>8<\/jats:sub>O<jats:sub>26<\/jats:sub>]\u2009\u22c5\u20090.5H<jats:sub>2<\/jats:sub>O, Ln=La, Ce, Pr, Nd and Sm (Series\u2005C1); (ii) {Ln(DMSO)<jats:sub>6<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>}[NaMo<jats:sub>8<\/jats:sub>O<jats:sub>26<\/jats:sub>] for Ln=Eu, Gd, Tb, Dy and Ho (Series\u2005C2) and (iii) [{Ln(DMSO)<jats:sub>7<\/jats:sub>}][NaMo<jats:sub>8<\/jats:sub>O<jats:sub>26<\/jats:sub>]\u2009\u22c5\u2009H<jats:sub>2<\/jats:sub>O for Ln=Dy, Ho, Er, Tm, Yb and Lu (Series\u2005C3). All solids reported here contain [\u2212\u03b2\u2010Mo<jats:sub>8<\/jats:sub>O<jats:sub>26<\/jats:sub>\u2212Na\u2212\u03b2\u2010Mo<jats:sub>8<\/jats:sub>O<jats:sub>26<\/jats:sub>\u2212] anionic chains, which is the dominant feature in the crystal packing of these solids. The chains interacted via hydrogen bonds with the solvated lanthanide counter cations. Lanthanide contraction brings about the difference in the primary coordination sphere of the Ln<jats:sup>3+<\/jats:sup> cations in the three series reported here. This manifests in the crystal structure as a change in the relative orientation of chains (or clusters) and the position of Ln<jats:sup>3+<\/jats:sup> centers, with water acting as the structure director. The study demonstrates Nature's parsimonious ability to optimize intermolecular interactions via diminutive deviations from recognizable packing patterns when a crystal nucleates from solution.<\/jats:p>","DOI":"10.1002\/asia.202401218","type":"journal-article","created":{"date-parts":[[2024,12,23]],"date-time":"2024-12-23T10:49:38Z","timestamp":1734950978000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Structural Variation In \u03b2\u2010Octamolybdate Polyoxoanion Based Crystals Across Lanthanide Series Isolated from a Water\/DMSO Solution"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7292-8658","authenticated-orcid":false,"given":"Shailabh","family":"Tewari","sequence":"first","affiliation":[{"name":"Solid State and Materials Chemistry Laboratory Department of Chemistry Indian Institute of Technology Delhi  Hauz Khas New Delhi India 110016"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5754-459X","authenticated-orcid":false,"given":"Arunachalam","family":"Ramanan","sequence":"additional","affiliation":[{"name":"Solid State and Materials Chemistry Laboratory Department of Chemistry Indian Institute of Technology Delhi  Hauz Khas New Delhi India 110016"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,1,8]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2024.08.011"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201913974"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00796"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.259.5101.1558"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg0604273"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12039-021-01953-y"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.18520\/cs\/v122\/i1\/39-46"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp408885k"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2016.12.010"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cp21209e"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200901348"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja801659m"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CE00865K"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2018.00631"},{"key":"e_1_2_8_15_1","unstructured":"S. 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