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Single\u2010atom catalysts (SACs) featuring transition metal\u2010nitrogen\u2010carbon (M\u2212N\u2212C) structures have demonstrated exceptional electrocatalytic efficacy in CO<jats:sub>2<\/jats:sub>RR by maximizing atom efficiency. Nevertheless, further investigation is warranted to optimize the catalytic performance of SACs through the selection of suitable carbon sources and supports, as well as the modulation of the microenvironment surrounding individual metal atoms. In this study, a sulfur\u2010doped Ni\u2212N\u2212C catalyst was prepared using a two\u2010step strategy involving metal ion adsorption and thermal decomposition, with porous ion exchange resin serving as the carbon source. Due to the uniform distribution of single atom active centers on the resin\u2010based carbon support and sulfur doping, this catalyst efficiently converts CO<jats:sub>2<\/jats:sub> into CO with a Faradaic efficiency exceeding 90\u2009% within the range of \u22120.69~\u22121.29\u2005V (vs. RHE), reaching a maximum value of 97.7\u2009% (\u22120.79\u2005V vs. RHE). Theoretical calculations indicate that second\u2010shell sulfur doping effectively promotes coupled transfer of protons and electrons, leading to a significant reduction in Gibbs free energy barriers for CO<jats:sub>2<\/jats:sub>RR intermediate products.<\/jats:p>","DOI":"10.1002\/asia.202401250","type":"journal-article","created":{"date-parts":[[2024,11,27]],"date-time":"2024-11-27T22:29:44Z","timestamp":1732746584000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Promoting CO<sub>2<\/sub> Electroreduction Over ion\u2010exchange Resin\u2010derived Ni\u2212N\u2212C Catalyst with Sulfur Doping"],"prefix":"10.1002","volume":"20","author":[{"given":"Yicheng","family":"Wang","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Technology Xi'an Jiaotong University  Xi'an 710049 P. R. 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