{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,7]],"date-time":"2026-05-07T02:28:13Z","timestamp":1778120893246,"version":"3.51.4"},"reference-count":32,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2025,2,11]],"date-time":"2025-02-11T00:00:00Z","timestamp":1739232000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2025,3,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The \n (X=Cl, Br, and I) complexes have been studied to understand the tendency towards the formation of hydrogen bonds and halogen bonds. Three different types of interactions <jats:italic>viz<\/jats:italic>., C\u2013X\nO, C\u2010H\nO, and O\u2010H\nX, are possible between the \n and \n. Experiments have been carried out in low temperature \n matrix using Fourier Transform Infrared spectroscopy. Electronic structure calculations have been performed to identify the possible binding motifs between \n and \n. Formation of more than one complex has been confirmed in \n (X=Br and I) mixture, using the experimental and simulated IR spectra, whereas only one type of complex is found in \n mixture. Energy decomposition analysis, quantum theory of atoms in molecules, and non\u2010covalent interaction analysis have been performed to understand the nature of interaction and the driving force for complexation under experimental conditions.<\/jats:p>","DOI":"10.1002\/asia.202401313","type":"journal-article","created":{"date-parts":[[2025,1,2]],"date-time":"2025-01-02T12:04:53Z","timestamp":1735819493000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Investigation of the Molecular Level Interaction in [CH<sub>3<\/sub>OH\u2212CH<sub>2<\/sub>X<sub>2<\/sub>] Complexes (X=I, Br, and Cl) using Matrix\u2010Isolation IR Spectroscopy"],"prefix":"10.1002","volume":"20","author":[{"given":"Sumit","family":"Kumar Agrawal","sequence":"first","affiliation":[{"name":"Department of Chemistry Birla Institute of Technology and Science, Pilani, Pilani Campus  Vidya Vihar Rajasthan 333031 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9252-209X","authenticated-orcid":false,"given":"Amrita","family":"Chakraborty","sequence":"additional","affiliation":[{"name":"Department of Chemistry Birla Institute of Technology and Science, Pilani, Pilani Campus  Vidya Vihar Rajasthan 333031 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1359-523X","authenticated-orcid":false,"given":"Shamik","family":"Chakraborty","sequence":"additional","affiliation":[{"name":"Department of Chemistry Birla Institute of Technology and Science, Pilani, Pilani Campus  Vidya Vihar Rajasthan 333031 India"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,2,11]]},"reference":[{"key":"e_1_2_9_1_1","author":"Shimizu S.","year":"2024","journal-title":"The Journal of Physical Chemistry B"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00484"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2021.117013"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2016.08.048"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CP03855E"},{"key":"e_1_2_9_6_1","doi-asserted-by":"crossref","unstructured":"D.\u2005M. Ivanov M.\u2005A. Kinzhalov A.\u2005S. Novikov I.\u2005V. Ananyev A.\u2005A. Romanova V.\u2005P. Boyarskiy M. Haukka V.\u2005Y. Kukushkin Crystal Growth & Design2017 17 1353.","DOI":"10.1021\/acs.cgd.6b01754"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108768105017374"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2052519213015078"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ce40285a"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1351\/PAC-REC-12-05-10"},{"key":"e_1_2_9_11_1","author":"Varadwaj P. R.","year":"2024","journal-title":"Crystal Growth & Design"},{"key":"e_1_2_9_12_1","volume":"881","author":"KM S.","year":"2001","journal-title":"Bhadbhade MM. Chem. Commun"},{"key":"e_1_2_9_13_1","doi-asserted-by":"crossref","unstructured":"S.\u2005F. Alshahateet R. Bishop D.\u2005C. Craig M.\u2005L. Scudder Crystal growth & design2011 11 4474.","DOI":"10.1021\/cg2006937"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CE00346C"},{"key":"e_1_2_9_15_1","doi-asserted-by":"crossref","unstructured":"F.\u2005M. Amombo\u2005Noa S.\u2005A. Bourne L.\u2005R. Nassimbeni Crystal Growth & Design2015 15 3271.","DOI":"10.1021\/acs.cgd.5b00402"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201807642"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.1270140404"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5NJ00300H"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100785a001"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100881a503"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0301-0104(97)00233-4"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2022.132853"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100147a010"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1669886"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.21380"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemphys.2022.111451"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/0584-8539(94)00168-B"},{"key":"e_1_2_9_28_1","unstructured":"TURBOMOLE V7.3 2018 a development of University of Karlsruhe and Forschungszentrum Karlsruhe GmbH 1989-2007 TURBOMOLE GmbH since 2007; available fromhttp:\/\/www.turbomole.com."},{"key":"e_1_2_9_29_1","volume":"2019","author":"Keith T. A.","year":"2019","journal-title":"TK Gristmill Software, Overland Park KS, USA"},{"key":"e_1_2_9_30_1","unstructured":"T. Lu Multiwfn: A Multifunctional Wave Function Analyzer version 3.3. 7 2015."},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jctc.7b00174"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cp00696c"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202401313","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T18:23:32Z","timestamp":1759947812000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202401313"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,2,11]]},"references-count":32,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2025,3,17]]}},"alternative-id":["10.1002\/asia.202401313"],"URL":"https:\/\/doi.org\/10.1002\/asia.202401313","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,2,11]]},"assertion":[{"value":"2024-09-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-02-11","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202401313"}}