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Development of integrated CO<jats:sub>2<\/jats:sub> capture and conversion protocols is necessary to mitigate this alarming challenge. Though CO<jats:sub>2<\/jats:sub> hydrogenation to produce formic acid and methanol has seen many strides in the past decades, most studies utilize pure CO<jats:sub>2<\/jats:sub> for this transformation. The CO<jats:sub>2<\/jats:sub> concentration in the atmosphere stands at 400 ppm and reports that utilize direct air capture as the strategy to capture CO<jats:sub>2<\/jats:sub> and utilize it for production of formic acid and methanol have only been reported in the past few years. This perspective summarizes such reports with a focus on the CO<jats:sub>2<\/jats:sub>\u2010capturing additive, reaction solvent, and the molecular catalyst used to affect the transformation.<\/jats:p>","DOI":"10.1002\/asia.202401327","type":"journal-article","created":{"date-parts":[[2025,1,22]],"date-time":"2025-01-22T08:20:26Z","timestamp":1737534026000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Catalytic Hydrogenation of CO<sub>2<\/sub> by Direct Air Capture to Valuable C1 Products Using Homogenous Catalysts"],"prefix":"10.1002","volume":"20","author":[{"given":"Ritu","family":"Bhardwaj","sequence":"first","affiliation":[{"name":"Organometallics &amp; Smart Materials Laboratory Department of Chemistry Indian Institute of Science Education and Research Bhopal  Bhopal Bypass Road Bhopal 462066 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