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In particular, methanol synthesis from CO<jats:sub>2<\/jats:sub> exhibits high potentials in terms of alternative energy sources to fossil fuels and NACs have shown promising performance in promoting the reaction. However, there still lacks of the bottom\u2010up catalysts design as well as the unanimous insight regarding the mechanistic understanding. Herein, we present a comprehensive overview of the physico\u2010chemical properties and the fabrication approach to NACs with high catalytic performance in the CO<jats:sub>2<\/jats:sub> hydrogenation to methanol. Additionally, the progresses of NACs were comprehensively summarized in terms of mechanisms. Finally, some thinking about the further relevant studies on NACs is outlooked with the aim to provide new insights for achieving the precise design and controllable properties of NACs.<\/jats:p>","DOI":"10.1002\/asia.202401387","type":"journal-article","created":{"date-parts":[[2024,11,28]],"date-time":"2024-11-28T01:59:23Z","timestamp":1732759163000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Nano\u2010alloy Catalysts for Methanol Synthesis from CO<sub>2<\/sub> Hydrogenation"],"prefix":"10.1002","volume":"20","author":[{"given":"Yanmin","family":"Zhang","sequence":"first","affiliation":[{"name":"Engineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education School of Chemical Engineering Zhengzhou University  Zhengzhou 450001 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