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Herein, we introduced the unique example of the aliphatic diethylenetriamine\u2010based nanofiltration membranes and tuned its selectivity by adding the terpolymer. To enhance the permeability of the salts while maintaining the rejection of the dye Eriochrome black T (EBT), a novel cationic\/zwitterionic terpolymer of Diallyldimethylammonium chloride (DADMAC), 3\u2010(<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2010diallyl\u2010<jats:italic>N<\/jats:italic>\u2010methylammonio)propanesulfonate (DAMAPS), and <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2010diallyldodecane\u20101,12\u2010diamine (DADA) was rationally synthesized and in\u2005situ grafted <jats:italic>via<\/jats:italic> interfacial polymerization (IP) in the polyamide active layer of the membrane. The incorporation of poly\u2010(DADMAC\u2010co\u2010DAMAPS\u2010co\u2010DADA) polymer into the diethylenetriamine polyamide active layer results in 5.8\u2005times increase in water flux while still retaining an outstanding rejection rate of ~99.9\u2009% for EBT. Furthermore, it exhibited enhanced salt permeability for NaCl, MgCl<jats:sub>2<\/jats:sub>, Na<jats:sub>2<\/jats:sub>SO<jats:sub>4<\/jats:sub>, and MgSO<jats:sub>4<\/jats:sub>. The grafted polymer increased the hydrophilicity of the membrane and strengthened stability for long\u2010term working conditions. Thus, the aliphatic diethylenetriamine membranes have great potential for desalination, and their active layer can be tuned with the zwitterionic moieties to enhance the salt permeability and keep the EBT rejection higher than 99\u2009%, which makes these membranes valuable for environmental and textile applications.<\/jats:p>","DOI":"10.1002\/asia.202401391","type":"journal-article","created":{"date-parts":[[2025,2,1]],"date-time":"2025-02-01T05:13:52Z","timestamp":1738386832000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Tailoring Nanofiltration Membranes by Incorporating Zwitterionic Quaternary Ammonium Terpolymer to Enhance Performance"],"prefix":"10.1002","volume":"20","author":[{"given":"Zeeshan","family":"Arshad","sequence":"first","affiliation":[{"name":"Chemistry Department King Fahd University of Petroleum &amp; Minerals (KFUPM)  Dhahran 31261 Saudi Arabia"},{"name":"The Applied Chemistry and Engineering Research Center of Excellence (ACER CoE) Mohammed VI Polytechnic University (UM6P) Lot 660  Hay Moulay Rachid Benguerir. 43150 Morocco"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2843-1980","authenticated-orcid":false,"given":"Nadeem","family":"Baig","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Membranes and Water Security, KFUPM  Dhahran 31261 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaikh A.","family":"Ali","sequence":"additional","affiliation":[{"name":"Chemistry Department King Fahd University of Petroleum &amp; 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