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However, the efficiency and stability of the catalysts used in this frontier technology are substantially lower than the requirement for practical application and need to be further improved, especially for gas\u2010phase reactions. In this work, the composites of iron single\u2010atom catalysts (Fe\u2010SACs) supported on N\/O\u2010doped carbon and graphitic carbon nitride (g\u2010C\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    ) were fabricated to promote the gas\u2010solid phase photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction under the simulated sunlight. Insightful characterizations reveal that g\u2010C\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    could function as a CO\n                    <jats:sub>2<\/jats:sub>\n                    capture and light\u2010absorber, while the Fe\u2010SACs act as a promotor for charge\u2010carrier separation. Hence, the catalytic performance was greatly increased compared to that of the individual component. For example, the individual thin g\u2010C\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    (T\u2010CN) and Fe\u2010SAC can generate total reduced CO\n                    <jats:sub>2<\/jats:sub>\n                    products of 5.06 and 0.75\u2005\u03bcmol.h\n                    <jats:sup>\u22121<\/jats:sup>\n                    g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , respectively. On the other hand, the reduced CO\n                    <jats:sub>2<\/jats:sub>\n                    products were increased by more than doubled (14.62\u2005\u03bcmol.h\n                    <jats:sup>\u22121<\/jats:sup>\n                    g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) when the composite of T\u2010CN\/Fe\u2010SAC was used as a catalyst. The photocatalytic enhancement could be attributed to the synergistic effects between Fe\u2010SAC\/T\u2010CN which possess the stronger CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption ability and charge separation capability and the increased number of active sites, resulting in the improved overall performance.\n                  <\/jats:p>","DOI":"10.1002\/asia.202401487","type":"journal-article","created":{"date-parts":[[2025,1,30]],"date-time":"2025-01-30T04:38:45Z","timestamp":1738211925000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Facilitating Charge Separation and CO\n                    <sub>2<\/sub>\n                    Adsorption in g\u2010C\n                    <sub>3<\/sub>\n                    N\n                    <sub>4<\/sub>\n                    by Fe Single Atoms on 2D Nitro\u2010Oxygeneous Carbon for Efficient Artificial Photosynthesis"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5129-3048","authenticated-orcid":false,"given":"Jitprabhat","family":"Ponchai","sequence":"first","affiliation":[{"name":"National Nanotechnology Center National Science and Technology Development Agency  111 Thailand Science Park Pathum Thani 12120 Thailand"},{"name":"Graduate Institute of Applied Science and Technology National Taiwan University of Science and Technology  Taipei 106 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1034-0079","authenticated-orcid":false,"given":"Weradesh","family":"Sangkhun","sequence":"additional","affiliation":[{"name":"National Nanotechnology Center National Science and Technology Development Agency  111 Thailand Science Park Pathum Thani 12120 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