{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:31:36Z","timestamp":1786977096213,"version":"build-2736575974"},"reference-count":64,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2025,3,4]],"date-time":"2025-03-04T00:00:00Z","timestamp":1741046400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100006049","name":"Comisi\u00f3n Sectorial de Investigaci\u00f3n Cient\u00edfica","doi-asserted-by":"publisher","award":["Programa de Apoyo a Grupos"],"award-info":[{"award-number":["Programa de Apoyo a Grupos"]}],"id":[{"id":"10.13039\/501100006049","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2025,4,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Heteronuclear zinc(II):mixed\u2010lanthanide(III) metal organic frameworks (MOFs) bearing the formula [\nZn\n                    <jats:sub>3<\/jats:sub>\n                    (oda)\n                    <jats:sub>6<\/jats:sub>\n                    (H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>6<\/jats:sub>\n                    ]\u22c5nH\n                    <jats:sub>2<\/jats:sub>\n                    O (Ln\u00a0=\u00a0lanthanide(III) ion, \n is smaller than \n, x+y=2, n=13 or 14) were obtained by direct reaction of the corresponding metal ion salts and oxydiacetate (\n                    <jats:sup>\u2212<\/jats:sup>\n                    OOC\u2010CH\n                    <jats:sub>2<\/jats:sub>\n                    \u2010O\u2010CH\n                    <jats:sub>2<\/jats:sub>\n                    \u2010COO\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) in aqueous solution, followed by slow solvent diffusion. This strategy led to the isolation of thirteen pure crystalline samples of isostructural hexagonal compounds (space group\n                    <jats:italic>P<\/jats:italic>\n                    6\/\n                    <jats:italic>mcc<\/jats:italic>\n                    ). Characterization by single\u2010crystal X\u2010ray diffraction was complemented by the analytical determination of the final \n molar ratio by microwave induced plasma atomic emission spectrometry. Results show that the experimentally determined \n molar ratio is systematically higher than that set out in the synthesis, especially for combinations of Ln that have larger size differences. Dual emission luminescence is observed for the compounds containing a combination of the more efficient visible\u2010emitting Ln (Sm, Eu, Tb, Dy). The selected aliphatic ligand does not promote antenna effect. Thus, tunable color luminescence can be achieved by selectively targeting each Ln preferential excitation wavelength. Dual emission is also observed for\n                    <jats:bold>CeEu<\/jats:bold>\n                    mixed\u2010MOF since the simultaneous excitation of both Ln is possible. Interestingly,\n                    <jats:bold>GdEu<\/jats:bold>\n                    mixed\u2010MOF also shows dual emission when only Gd is directly excited.\n                  <\/jats:p>","DOI":"10.1002\/asia.202401496","type":"journal-article","created":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T00:34:03Z","timestamp":1741739643000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Tunable Dual\u2010emission of Mixed\u2010lanthanide MOFs with no Antenna Effect"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-7305-7007","authenticated-orcid":false,"given":"Franco","family":"Castro","sequence":"first","affiliation":[{"name":"\u00c1rea Qu\u00edmica Inorg\u00e1nica Departamento Estrella Campos (DEC) Facultad de Qu\u00edmica Universidad de la Rep\u00fablica  Gral. Flores 2124 11400 Montevideo Uruguay"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fernando","family":"Igoa Salda\u00f1a","sequence":"additional","affiliation":[{"name":"\u00c1rea Qu\u00edmica Inorg\u00e1nica Departamento Estrella Campos (DEC) Facultad de Qu\u00edmica Universidad de la Rep\u00fablica  Gral. Flores 2124 11400 Montevideo Uruguay"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6762-5852","authenticated-orcid":false,"given":"Mariela","family":"Pist\u00f3n","sequence":"additional","affiliation":[{"name":"GATPREM \u00c1rea Qu\u00edmica Anal\u00edtica Departamento Estrella Campos (DEC) Facultad de Qu\u00edmica Universidad de la Rep\u00fablica  Gral. Flores 2124 11400 Montevideo Uruguay"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3339-2998","authenticated-orcid":false,"given":"Javier","family":"Gonz\u00e1lez\u2010Platas","sequence":"additional","affiliation":[{"name":"Departamento de F\u00edsica Instituto Universitario de Estudios Avanzados en F\u00edsica At\u00f3mica Molecular y Fot\u00f3nica (IUDEA) MALTA-Consolider Team Universidad de La Laguna  Avenida Astrof\u00edsico Francisco S\u00e1nchez s\/n 38000 La Laguna Tenerife Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7498-5226","authenticated-orcid":false,"given":"Carlos","family":"Kremer","sequence":"additional","affiliation":[{"name":"\u00c1rea Qu\u00edmica Inorg\u00e1nica Departamento Estrella Campos (DEC) Facultad de Qu\u00edmica Universidad de la Rep\u00fablica  Gral. 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