{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T17:24:47Z","timestamp":1786209887826,"version":"build-2736575974"},"reference-count":72,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2025,2,20]],"date-time":"2025-02-20T00:00:00Z","timestamp":1740009600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006464","name":"Birla Institute of Technology and Science, Pilani","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100006464","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2025,4,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Nickel\u2010based molybdates have attracted considerable attention owing to their distinctive isomorphous structure. In this study, pristine NiMoO\n                    <jats:sub>4<\/jats:sub>\n                    and Co\u2010doped Ni\n                    <jats:sub>1\u2010x<\/jats:sub>\n                    Co\n                    <jats:sub>x<\/jats:sub>\n                    MoO\n                    <jats:sub>4<\/jats:sub>\n                    were synthesized and investigated for their electrocatalytic activity in methanol oxidation and methanol\u2010assisted water splitting reactions. Through a comprehensive exploration of the structure\u2010property relationship, it was found that the optimal coexistence of \u03b1 and \u03b2 molybdate phases, induced by Co doping, led to lattice strain and facilitated the presence of essential catalytic descriptors such as higher oxidation states of Ni and surface oxygen vacancies within the lattice. These factors contributed to the enhanced electrocatalytic activity of Ni\n                    <jats:sub>0.7<\/jats:sub>\n                    Co\n                    <jats:sub>0.3<\/jats:sub>\n                    MoO\n                    <jats:sub>4<\/jats:sub>\n                    in methanol oxidation and hydrogen evolution reaction. Detailed kinetic studies were conducted to further elucidate the mechanisms involved. Overall, these findings highlight the promising potential of Ni\n                    <jats:sub>0.7<\/jats:sub>\n                    Co\n                    <jats:sub>0.3<\/jats:sub>\n                    MoO\n                    <jats:sub>4<\/jats:sub>\n                    as an effective catalyst for electrochemical methanol upgrading in conjunction with water splitting, with implications for sustainable energy conversion technologies.\n                  <\/jats:p>","DOI":"10.1002\/asia.202401520","type":"journal-article","created":{"date-parts":[[2025,2,4]],"date-time":"2025-02-04T02:51:36Z","timestamp":1738637496000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Engineering Lattice Strain in Co\u2010Doped NiMoO\n                    <sub>4<\/sub>\n                    for boosting Methanol Oxidation Reaction"],"prefix":"10.1002","volume":"20","author":[{"given":"Preetha Chandrasekharan","family":"Meenu","sequence":"first","affiliation":[{"name":"Department of Chemistry Birla Institute of Technology and Science Pilani  Hyderabad Campus Hyderabad 500078 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Naga Pranava Sree","family":"Kothoori","sequence":"additional","affiliation":[{"name":"Department of Chemistry School of Science GITAM University  Hyderabad 502329 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Preeti","family":"Dahiya","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Roorkee  Roorkee 247 667 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tapas Kumar","family":"Mandal","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Roorkee  Roorkee 247 667 India"},{"name":"Centre for Nanotechnology Indian Institute of Technology Roorkee  Roorkee 247 667 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