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Here, the thio\u2010amide group present in 5\u2010alkylidene\u2010rhodanine has been utilized as latent thiol functionality and C\u2212N coupling with amines is realized. The reaction occurs evading the use of metal catalysts, inert atmosphere, high temperature or microwave heating, and strong base which is normally required for metal catalyzed C\u2212N coupling reaction. Pertinently, here poorly nucleophilic aromatic amines react very efficiently. Desulfitative C\u2212N coupling involving free thiol moiety and poorly nucleophilic aromatic amines in metal free condition has never been accomplished in one step, without requiring high temperature microwave heating or strong bases. The reaction occurs at just 50\u2009\u00b0C in few hours under ambient atmosphere. Moreover, here no H<jats:sub>2<\/jats:sub>S is released in the environment, since solid sulphur is precipitated out as side product, making this protocol environmentally friendly. 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