{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,23]],"date-time":"2026-08-23T16:31:33Z","timestamp":1787502693546,"version":"build-2736575974"},"reference-count":68,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T00:00:00Z","timestamp":1741737600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["CRG\/2021\/005928\/OC"],"award-info":[{"award-number":["CRG\/2021\/005928\/OC"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2025,5,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Herein, for the first time, we have reported a route to the introduction of benzo[1,3]oxathiol\u20102\u2010one group onto pillar[5]arene to synthesize a new copillar[5]arene, which gives a new pillar[5]arene derivative\n                    <jats:bold>1<\/jats:bold>\n                    upon further functionalization. The well\u2010defined cavity of this new copillar[5]arene exhibits solvent inclusion properties as characterized by single\u2010crystal X\u2010ray structures. The present study explores the inclusion of ethyl acetate (EtOAc) and acetonitrile (CH\n                    <jats:sub>3<\/jats:sub>\n                    CN) and the supramolecular assemblies with different features in the solid state. Copillar[5]arene\n                    <jats:bold>1<\/jats:bold>\n                    shows inclination to form dimers in both EtOAc and CH\n                    <jats:sub>3<\/jats:sub>\n                    CN. While ethyl acetate\u2010occupied macrocycles give 2D arrangement involving \u03c0\u2013\u03c0 interaction, acetonitrile\u2010occupied macrocycles follow \u03c0\u2013\u03c0, C\u2212H\u22c5\u22c5\u22c5\u03c0, and H\u2010bond interactions in 2D arrangement and create a rhombus\u2010shaped molecular channel with a diameter of ~5.5\u2005\u00c5 in 3D packing. Compound\n                    <jats:bold>1<\/jats:bold>\n                    shows good photophysical behavior and aggregation. It acts as a chromogenic sensor for the selective recognition of sulfide (S\n                    <jats:sup>2\u2212<\/jats:sup>\n                    ) over a series of other anions in both organic and aqueous\u2010organic solvents. The detection limit for S\n                    <jats:sup>2\u2212<\/jats:sup>\n                    is determined to be 3.81\u00d710\n                    <jats:sup>\u22127<\/jats:sup>\n                    \u2005M.\n                  <\/jats:p>","DOI":"10.1002\/asia.202401653","type":"journal-article","created":{"date-parts":[[2025,3,11]],"date-time":"2025-03-11T18:46:28Z","timestamp":1741718788000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Benzo[1,3]oxathiol\u20102\u2010one Motif\u2010Based a New Chromogenic Copillar[5]arene: Synthesis, Solid\u2010State Assembly, Photophysical Studies, and Colorimetric Recognition of S\n                    <sup>2\u2212<\/sup>"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-7464-0544","authenticated-orcid":false,"given":"Subrata Ranjan","family":"Dhara","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Kalyani  Kalyani Nadia 741235 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nabajyoti","family":"Baildya","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Kalyani  Kalyani Nadia 741235 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1236-8139","authenticated-orcid":false,"given":"Kumaresh","family":"Ghosh","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Kalyani  Kalyani Nadia 741235 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,3,12]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/9780470740880"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja110384v"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C1CS15220C"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja909041g"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35141b"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/b705458k"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1080\/07328303.2021.1967970"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35075k"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC01850K"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar500075g"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00341"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja711260m"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00765"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213313"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar2003418"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC09088A"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssensors.1c01510"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702175"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2020.03.074"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2023.108740"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar500177d"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC00531D"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b01123"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2023.108740"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC03641D"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3082523"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2024.215762"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QM01176C"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.2c00272"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c00397"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC01042F"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b02092"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2023.154891"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1093\/bulcsj\/uoae093"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc35498e"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c07482"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2021.713305"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c16248"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja203661j"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1471-4159.2004.02617.x"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0006-291X(02)00422-9"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/hep.20817"},{"key":"e_1_2_8_43_1","volume":"11","author":"Su L.","year":"2022","journal-title":"Biosens.Bioelectron."},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2018.08.028"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.3390\/s23063316"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/bs.mie.2014.11.013"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ab.2003.09.037"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2019.108049"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2021.109451"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.07.003"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.8b02795"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo1020823"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200904765"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/B818330A"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1039\/B203191B"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC05776B"},{"key":"e_1_2_8_57_1","unstructured":"M.\u2005J. Frisch G. Trucks H.\u2005B. Schlegel G. Scuseria M. Robb J. Cheeseman G. Scalmani V. Barone B. Mennucci G. Petersson et\u2005al Gaussian 09 revision D. 1 Gaussian Inc. Wallingford CT 2009."},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochem.2017.08.024"},{"key":"e_1_2_8_59_1","unstructured":"Bruker APEX2 SAINT SADABS BRUKER AXS Inc. Madison Wisconsin USA 2008."},{"key":"e_1_2_8_60_1","unstructured":"G.\u2005M. Sheldrick Sadabs. Program for Multi-Scan Absorption Correction of Area Detector Data University of Gottingen Germany 2002."},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889898007717"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_8_63_1","unstructured":"International Tables for Crystallography Vol C Tables\u20056.1.1.4 4.2.6.8 4.2.4.2; Kluwer: Boston 1995."},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889808042726"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576719014092"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.comptc.2015.05.007"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/0301-0104(81)85090-2"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(96)00349-1"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202401653","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T19:20:41Z","timestamp":1759951241000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202401653"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,3,12]]},"references-count":68,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2025,5,2]]}},"alternative-id":["10.1002\/asia.202401653"],"URL":"https:\/\/doi.org\/10.1002\/asia.202401653","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,3,12]]},"assertion":[{"value":"2024-11-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-03-12","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202401653"}}