{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,5]],"date-time":"2026-05-05T02:40:08Z","timestamp":1777948808591,"version":"3.51.4"},"reference-count":83,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2025,2,1]],"date-time":"2025-02-01T00:00:00Z","timestamp":1738368000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,2,1]],"date-time":"2025-02-01T00:00:00Z","timestamp":1738368000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2025,5,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Thermoelectric properties of undoped crystals of dibenzo[\n                    <jats:italic>g,p<\/jats:italic>\n                    ]chrysene (DBC), deuterated DBC (DBC\u2010\n                    <jats:italic>d<\/jats:italic>\n                    <jats:sub>16<\/jats:sub>\n                    ), and 2,10\u2010dimethyl\u2010DBC (DBC\u2010Me\n                    <jats:sub>2<\/jats:sub>\n                    ) have been studied to obtain some insights into the relationship between the structural parameters of materials and the giant Seebeck effect. X\u2010ray crystallography showed one\u2010dimensional columnar packing with the interlayer distances (\n                    <jats:italic>d<\/jats:italic>\n                    ) for DBC\u2010\n                    <jats:italic>d<\/jats:italic>\n                    <jats:sub>16<\/jats:sub>\n                    , DBC, and DBC\u2010Me\n                    <jats:sub>2<\/jats:sub>\n                    were 3.78\u2005\u00c5, 3.79\u2005\u00c5, and 3.91\u2005\u00c5, respectively. All three compounds formed one\u2010dimensional carrier transport pathways as suggested by the transfer integral calculations. Their Seebeck coefficients (\u03b1) were negative, indicating n\u2010type behavior. DBC\u2010\n                    <jats:italic>d<\/jats:italic>\n                    <jats:sub>16<\/jats:sub>\n                    exhibited among the highest peak Seebeck coefficient (\u03b1\n                    <jats:sub>max<\/jats:sub>\n                    =\u2212114\u2005mV\/K) compared to DBC and DBC\u2010Me\n                    <jats:sub>2<\/jats:sub>\n                    (\u03b1\n                    <jats:sub>max<\/jats:sub>\n                    =\u221231 and \u221222\u2005mV\/K, respectively). The power factors of DBC\u2010\n                    <jats:italic>d<\/jats:italic>\n                    <jats:sub>16<\/jats:sub>\n                    and DBC\u2010Me\n                    <jats:sub>2<\/jats:sub>\n                    were higher than that of DBC, due to an increase in Seebeck coefficient and conductivity, respectively. Notably, a positive correlation was found between the peak temperature of the Seebeck coefficient and interlayer distance\n                    <jats:italic>d<\/jats:italic>\n                    , while |\u03b1\n                    <jats:sub>max<\/jats:sub>\n                    | correlated negatively with\n                    <jats:italic>d<\/jats:italic>\n                    . Deuteration significantly enhanced |\u03b1\n                    <jats:sub>max<\/jats:sub>\n                    |, likely due to reduced molecular vibrations, though further investigation should consider the effect of dynamic structural fluctuation caused by thermal motion.\n                  <\/jats:p>","DOI":"10.1002\/asia.202401692","type":"journal-article","created":{"date-parts":[[2025,1,4]],"date-time":"2025-01-04T10:39:34Z","timestamp":1735987174000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Giant Seebeck Effect of Dibenzo[\n                    <i>g,p<\/i>\n                    ]chrysene and its Derivatives: Deuteration and Substituent Effects and Relationship with Interlayer Distance"],"prefix":"10.1002","volume":"20","author":[{"given":"Hirotaka","family":"Kojima","sequence":"first","affiliation":[{"name":"Division of Materials Science Nara Institute of Science and Technology  8916-5 Takayama-cho Ikoma Nara 630-0192 Japan"},{"name":"National Institute of Technology (KOSEN) Maizuru College  234 Shiroya Maizuru Kyoto 625-8511 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kohei","family":"Kojima","sequence":"additional","affiliation":[{"name":"Division of Materials Science Nara Institute of Science and Technology  8916-5 Takayama-cho Ikoma Nara 630-0192 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Toshiki","family":"Kawauchi","sequence":"additional","affiliation":[{"name":"Division of Materials Science Nara Institute of Science and Technology  8916-5 Takayama-cho Ikoma Nara 630-0192 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ryo","family":"Abe","sequence":"additional","affiliation":[{"name":"Division of Materials Science Nara Institute of Science and Technology  8916-5 Takayama-cho Ikoma Nara 630-0192 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4540-5816","authenticated-orcid":false,"given":"Masakazu","family":"Nakamura","sequence":"additional","affiliation":[{"name":"Division of Materials Science Nara Institute of Science and Technology  8916-5 Takayama-cho Ikoma Nara 630-0192 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Masakazu","family":"Yamagishi","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry and Chemical Engineering National Institute of Technology (KOSEN) Toyama College  13 Hongo-machi, Toyama city Toyama 939-8630 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Naoto","family":"Hamaguchi","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science Kanagawa University  3-27-1 Rokkaku-bashi, Kanagawa-ku Yokohama 221-8686 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Katsunori","family":"Yamanishi","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science Kanagawa University  3-27-1 Rokkaku-bashi, Kanagawa-ku Yokohama 221-8686 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7663-5879","authenticated-orcid":false,"given":"Hayato","family":"Tsuji","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science Kanagawa University  3-27-1 Rokkaku-bashi, Kanagawa-ku Yokohama 221-8686 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,2,1]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1080\/14686996.2018.1530938"},{"key":"e_1_2_7_2_1","volume":"30","author":"Zhang C.","year":"2020","journal-title":"Adv. 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