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Herein, a photo\u2010driven metal\u2010free catalytic system has been successfully applied to a novel coupling\u2010cyclization reaction between arylamines and formaldehyde, enabling the direct synthesis of various 1,3\u2010diarylimidazolines from primary amines. Notably, this method also facilitates the chemical conversion of polyoxymethylene plastics under these conditions. The present work provides new insights and directions for both imidazoline synthesis and plastic degradation.<\/jats:p>","DOI":"10.1002\/asia.202401742","type":"journal-article","created":{"date-parts":[[2025,1,15]],"date-time":"2025-01-15T22:20:48Z","timestamp":1736979648000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Photo\u2010Driven Direct Construction of Imidazolidines from Anilines and Paraformaldehyde and Its Application in Polyoxymethylene Plastics Usage"],"prefix":"10.1002","volume":"20","author":[{"given":"Sheng","family":"Bi","sequence":"first","affiliation":[{"name":"Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 Liaoning China"},{"name":"Leibniz-Institut f\u00fcr Katalyse e.\u2009V.  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