{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T04:56:27Z","timestamp":1785905787111,"version":"3.56.0"},"reference-count":48,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2025,4,9]],"date-time":"2025-04-09T00:00:00Z","timestamp":1744156800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,4,9]],"date-time":"2025-04-09T00:00:00Z","timestamp":1744156800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22271282"],"award-info":[{"award-number":["22271282"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2025,5,15]]},"abstract":"Abstract<\/jats:title>\n \n Given the high similarity in physical and chemical properties, especially in terms of molecular size and boiling point, of acetylene (C\n 2<\/jats:sub>\n H\n 2<\/jats:sub>\n ), carbon dioxide (CO\n 2<\/jats:sub>\n ), and ethylene (C\n 2<\/jats:sub>\n H\n 4<\/jats:sub>\n ) molecules, traditional separation techniques encounter great challenges. Fortunately, metal organic framework (MOF) materials have demonstrated significant potential for efficient separation of these gases at the molecular level due to their finely tunable pore structure and surface functional properties. In this paper, we have successfully synthesized a cadmium\u2010based MOF (\n FJI\u2010W\u2010708<\/jats:bold>\n ), which exhibits negative electrostatic potential pores and exceptional thermal stability. It is worth noting that\n FJI\u2010W\u2010708<\/jats:bold>\n exhibits high C\n 2<\/jats:sub>\n H\n 2<\/jats:sub>\n capacity (61\u2005cm\n 3<\/jats:sup>\n \/g), as well as appropriate selectivity towards C\n 2<\/jats:sub>\n H\n 2<\/jats:sub>\n \/CO\n 2<\/jats:sub>\n (3.39) and C\n 2<\/jats:sub>\n H\n 2<\/jats:sub>\n \/C\n 2<\/jats:sub>\n H\n 4<\/jats:sub>\n (3.47). The dynamic breakthrough experiments of C\n 2<\/jats:sub>\n H\n 2<\/jats:sub>\n \/CO\n 2<\/jats:sub>\n (50\/50) mixture and C\n 2<\/jats:sub>\n H\n 2<\/jats:sub>\n \/C\n 2<\/jats:sub>\n H\n 4<\/jats:sub>\n (1\/99) mixture clearly demonstrated the actual separation performance. The breakthrough time for C\n 2<\/jats:sub>\n H\n 2<\/jats:sub>\n \/CO\n 2<\/jats:sub>\n (50\/50) was observed to be 23\u2005min\/g, while for a C\n 2<\/jats:sub>\n H\n 2<\/jats:sub>\n \/C\n 2<\/jats:sub>\n H\n 4<\/jats:sub>\n (1\/99) mixture it could reach up 46\u2005min\/g, demonstrating excellent recyclability and achieving a benchmark productivity of C\n 2<\/jats:sub>\n H\n 4<\/jats:sub>\n at 4.12\u2005mmol\/g.\n <\/jats:p>","DOI":"10.1002\/asia.202401789","type":"journal-article","created":{"date-parts":[[2025,3,8]],"date-time":"2025-03-08T18:26:19Z","timestamp":1741458379000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["A Cadmium Metal\u2010Organic Framework with Negative Electrostatic Potentials for Efficient Separation of C\n 2<\/sub>\n H\n 2<\/sub>\n \/CO\n 2<\/sub>\n and C\n 2<\/sub>\n H\n 2<\/sub>\n \/C\n 2<\/sub>\n H\n 4<\/sub>"],"prefix":"10.1002","volume":"20","author":[{"given":"Xiang","family":"Meng","sequence":"first","affiliation":[{"name":"College of Chemistry Fuzhou University Fuzhou Fujian 350108 China"},{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongqin","family":"Zhu","sequence":"additional","affiliation":[{"name":"College of Chemistry Fuzhou University Fuzhou Fujian 350108 China"},{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuixiang","family":"Zou","sequence":"additional","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiawei","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingyan","family":"Wu","sequence":"additional","affiliation":[{"name":"College of Chemistry Fuzhou University Fuzhou Fujian 350108 China"},{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7651-0291","authenticated-orcid":false,"given":"Cheng","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Chemistry Fuzhou University Fuzhou Fujian 350108 China"},{"name":"State Key Lab of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,4,9]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2023.124557"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202311419"},{"key":"e_1_2_7_4_1","unstructured":"\u00a0"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaf2458"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adh0135"},{"key":"e_1_2_7_7_1","unstructured":"\u00a0"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202203745"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c03442"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC03029J"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2023.125777"},{"key":"e_1_2_7_12_1","unstructured":"\u00a0"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7TA05598F"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.3c03058"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201700779"},{"key":"e_1_2_7_16_1","unstructured":"\u00a0"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2NR04187A"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms14085"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202214887"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804442"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b03850"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA11340A"},{"key":"e_1_2_7_23_1","unstructured":"\u00a0"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/D4DT00246F"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013965"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c09917"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c10620"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b05431"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.4c00666"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2022.121404"},{"key":"e_1_2_7_31_1","unstructured":"\u00a0"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309925"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2017.11.044"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c03517"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms1206"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2023.124377"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.202100169"},{"key":"e_1_2_7_38_1","unstructured":"\u00a0"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.9b01691"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105880"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202014680"},{"key":"e_1_2_7_42_1","unstructured":"\u00a0"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201903952"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.128454"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-33271-3"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2056989019016244"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2QI00890D"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.18396"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202401789","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.202401789","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202401789","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,5,3]],"date-time":"2026-05-03T20:56:49Z","timestamp":1777841809000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202401789"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,4,9]]},"references-count":48,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2025,5,15]]}},"alternative-id":["10.1002\/asia.202401789"],"URL":"https:\/\/doi.org\/10.1002\/asia.202401789","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,4,9]]},"assertion":[{"value":"2024-12-06","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-04-09","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202401789"}}