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Additionally, accurately characterizing the ground\u2010state electronic configuration of these complexes remains a significant challenge. In this article, we report a unique and rare square planar cobalt complex, [Co(L1\u22c5\n                    <jats:sup>\u2212<\/jats:sup>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ] (\n                    <jats:bold>1<\/jats:bold>\n                    ), where the coordination sites are occupied by the phenanthroiminoquinone (L1). The molecular structure of complex\n                    <jats:bold>1<\/jats:bold>\n                    was determined using single\u2010crystal X\u2010ray diffraction studies. A structurally analogous nickel complex, [Ni\n                    <jats:sup>II<\/jats:sup>\n                    (L1\u22c5\n                    <jats:sup>\u2212<\/jats:sup>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ] (\n                    <jats:bold>2<\/jats:bold>\n                    ), was also synthesized and characterized. Detailed DC magnetic susceptibility measurements of\n                    <jats:bold>2<\/jats:bold>\n                    reveal strong antiferromagnetic exchange interactions between the radical centers, rendering it diamagnetic. For cobalt complex\n                    <jats:bold>1<\/jats:bold>\n                    , this strong antiferromagnetic coupling results in a doublet ground state, as corroborated by X\u2010band EPR measurements (at 5\u2005K) conducted on both polycrystalline and frozen solution samples. To gain deeper insights into the electronic structure of the cobalt ion in\n                    <jats:bold>1<\/jats:bold>\n                    , a comprehensive suite of experimental and theoretical investigations was conducted, including X\u2010ray diffraction, DC magnetic studies, X\u2010band EPR, UV\u2010Vis\u2010NIR spectroscopy, and ab initio calculations. These studies collectively indicate that the cobalt ion in\n                    <jats:bold>1<\/jats:bold>\n                    exists in a divalent low\u2010spin state. Furthermore, the observed slow relaxation of magnetization for the doublet state of\n                    <jats:bold>1<\/jats:bold>\n                    highlights its potential as an ideal candidate for designing spin\u2010based molecular qubits.\n                  <\/jats:p>","DOI":"10.1002\/asia.202401798","type":"journal-article","created":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T01:36:26Z","timestamp":1741743386000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Probing the Slow Relaxation of Magnetization of a Square Planar Cobalt Complex with Doublet Ground State"],"prefix":"10.1002","volume":"20","author":[{"given":"Kamal Uddin","family":"Ansari","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Bombay Powai  Mumbai, Maharashtra 400076 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