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The prepared metal complexes were further cocrystallized with selected iodoperfluorinated benzenes. Out of 20 combinations, 14 experiments yielded crystals suitable for single\u2010crystal X\u2010ray diffraction. Structural analysis revealed that in 7 cocrystals halogen bonds are formed both with morpholinyl oxygen as well as with chloride atoms. In 6 cocrystals only I\u22c5\u22c5\u22c5Cl halogen bonds are present, while only one cocrystal exclusively featured I\u22c5\u22c5\u22c5O\n                    <jats:sub>morpholinyl<\/jats:sub>\n                    halogen bonds. We observed 5 halogen bonding motifs to the MCl\n                    <jats:sub>2<\/jats:sub>\n                    moiety, in which each chloride atom can be an acceptor of one halogen bond, two, or none at all. The most common motif in our work (6 cocrystals) is where one chlorine atom is an acceptor of one halogen bond, while the other chlorine atom does not participate in halogen bonding. The crystal packing in the prepared cocrystals is directed by halogen\u2010bonded architectures which are either zero\u2010, one\u2010 or two\u2010dimensional.\n                  <\/jats:p>","DOI":"10.1002\/asia.202401916","type":"journal-article","created":{"date-parts":[[2025,1,31]],"date-time":"2025-01-31T09:43:42Z","timestamp":1738316622000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Competition\n                    <i>vs<\/i>\n                    . Cooperativity of I\u22c5\u22c5\u22c5O\n                    <sub>morpholinyl<\/sub>\n                    and I\u22c5\u22c5\u22c5Cl\u2212M Halogen Bonds in Cocrystals of Zinc(II) and Copper(II) Coordination Compounds Carrying Multiple Acceptor Sites"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7862-6888","authenticated-orcid":false,"given":"Vinko","family":"Nemec","sequence":"first","affiliation":[{"name":"Department of Chemistry Faculty of Science University of Zagreb  Horvatovac 102a Zagreb Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9130-1762","authenticated-orcid":false,"given":"Ru\u0111er","family":"Su\u0161anj","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science University of Zagreb  Horvatovac 102a Zagreb Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1798-9348","authenticated-orcid":false,"given":"Nea","family":"Baus Topi\u0107","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science University of Zagreb  Horvatovac 102a Zagreb Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4081-2420","authenticated-orcid":false,"given":"Dominik","family":"Cin\u010di\u0107","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science University of Zagreb  Horvatovac 102a Zagreb Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,2,11]]},"reference":[{"key":"e_1_2_10_1_1","doi-asserted-by":"publisher","DOI":"10.1351\/PAC-REC-12-05-10"},{"key":"e_1_2_10_2_1","unstructured":"\u00a0"},{"key":"e_1_2_10_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00484"},{"key":"e_1_2_10_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/a903182k"},{"key":"e_1_2_10_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar400103r"},{"key":"e_1_2_10_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cg400988m"},{"key":"e_1_2_10_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC08135B"},{"key":"e_1_2_10_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CE26150B"},{"key":"e_1_2_10_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar400103r"},{"key":"e_1_2_10_10_1","unstructured":"\u00a0"},{"key":"e_1_2_10_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/b812927d"},{"key":"e_1_2_10_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2009.09.035"},{"key":"e_1_2_10_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2015.09.005"},{"key":"e_1_2_10_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.5b01211"},{"key":"e_1_2_10_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/b605420j"},{"key":"e_1_2_10_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200600523"},{"key":"e_1_2_10_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1dt10911a"},{"key":"e_1_2_10_18_1","unstructured":"\u00a0"},{"key":"e_1_2_10_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2003.11.031"},{"key":"e_1_2_10_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201000049"},{"key":"e_1_2_10_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1CE00158B"},{"key":"e_1_2_10_22_1","unstructured":"\u00a0"},{"key":"e_1_2_10_23_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1ce05447c"},{"key":"e_1_2_10_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.5b00535"},{"key":"e_1_2_10_25_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CE00638H"},{"key":"e_1_2_10_26_2","doi-asserted-by":"crossref","unstructured":"R.\u2005W. 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