{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T12:15:02Z","timestamp":1790252102250,"version":"4.1.0"},"reference-count":64,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2025,6,17]],"date-time":"2025-06-17T00:00:00Z","timestamp":1750118400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,6,17]],"date-time":"2025-06-17T00:00:00Z","timestamp":1750118400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2025,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Lanthanide [Ln(III)] ions are known for their unique near\u2010infrared (NIR) luminescence, typically achieved through indirect excitation via the antenna effect. Organic ligands, such as\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    \u2010bis(3\u2010methoxysalicylidene)\u20101,4\u2010diamino butane (\n                    <jats:bold>L<\/jats:bold>\n                    ), in combination with Zn, have previously demonstrated their effectiveness in enhancing lanthanide NIR emission, as seen in bimetallic [\n                    <jats:bold>L\u2010Zn\u2010Ln<\/jats:bold>\n                    ] complexes, which employs a single antenna. In this study, we present a new series of trimetallic Zn\u2013Ln complexes, [\n                    <jats:bold>(L\u2010Zn)\u2082\u2010Ln<\/jats:bold>\n                    ], featuring two compartmental ligand\u2010Zn complexes, acting as antennas, aimed at further improving energy transfer efficiency to the lanthanide centers. Comprehensive characterization using SCXRD, PXRD, FT\u2010IR, and CHN analyses confirmed the structural integrity of these complexes. Notably, SCXRD and XPS revealed significant structural differences between the bimetallic and trimetallic systems. The impact of the additional antenna, replacing nitrate and methanol\u2014known contributors to nonradiative relaxation in the bimetallic [\n                    <jats:bold>L\u2010Zn\u2010Ln<\/jats:bold>\n                    ] complexes\u2014was thoroughly examined. Photophysical studies across both visible and NIR regions demonstrated substantial enhancements in luminescence, particularly in the NIR region, attributed to the inclusion of the second antenna, highlighting its role in improving the overall energy transfer process.\n                  <\/jats:p>","DOI":"10.1002\/asia.202500017","type":"journal-article","created":{"date-parts":[[2025,6,17]],"date-time":"2025-06-17T12:40:54Z","timestamp":1750164054000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Dual\u2010Antenna Trimetallic Lanthanide Complexes for Enhanced Near\u2010Infrared Luminescence"],"prefix":"10.1002","volume":"20","author":[{"given":"Krishanu","family":"Bandyopadhyay","sequence":"first","affiliation":[{"name":"Department of Chemistry Institute of Science Banaras Hindu University  Varanasi 221005 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abhineet","family":"Verma","sequence":"additional","affiliation":[{"name":"Department of Chemistry Malaviya National Institute of Technology (MNIT)  Jaipur 302017 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6915-9384","authenticated-orcid":false,"given":"Satyen","family":"Saha","sequence":"additional","affiliation":[{"name":"Department of Chemistry Institute of Science Banaras Hindu University  Varanasi 221005 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,6,17]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1305910110"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2019.02.036"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201913441"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2011.09.018"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja056303g"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc53056f"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochemrev.2017.11.001"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc22126a"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/bs.hpcre.2021.05.001"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202001768"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3AY02089D"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b04938"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00828D"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10895-024-03677-x"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9DT01197H"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0168-1273(07)37035-9"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b00984"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201703911"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC03934A"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochemrev.2004.10.003"},{"key":"e_1_2_8_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2023.121406"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm8024445"},{"key":"e_1_2_8_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/bio.4810"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp9119183"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2018.11.013"},{"key":"e_1_2_8_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2021.131531"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361-6528\/ab55c3"},{"key":"e_1_2_8_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT02563J"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2015.10.048"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TC01477B"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC00433A"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b02096"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b02103"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2019.03.021"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2009.12.028"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2008.06.009"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic050512k"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0NJ04020G"},{"key":"e_1_2_8_32_1","first-page":"10263","volume":"46","author":"Joy C.","year":"2009","journal-title":"Dalton Trans."},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.5946"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b00165"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2dt31268a"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2013.07.004"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3tc31814a"},{"key":"e_1_2_8_38_1","first-page":"7697","volume":"3","author":"Ghorai P.","year":"2018","journal-title":"ChemSelect"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0925-8388(99)00712-4"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1010-6030(97)00303-1"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA01677B"},{"key":"e_1_2_8_41_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213587"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcb.3c01674"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.8b00948"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2019.02.037"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jlumin.2017.06.045"},{"key":"e_1_2_8_46_1","volume-title":"Infrared and Raman Spectra of Inorganic and Coordination Compounds","author":"Nakamoto K.","year":"2009"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2022.121121"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.60.1299"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/0040-6031(89)87042-X"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2014.04.009"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3nj00466j"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(93)85056-A"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/ed046pA628.1"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202005459"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2020.536907"},{"key":"e_1_2_8_56_1","first-page":"213","volume-title":"Handbook on the Physics and Chemistry of Rare Earths","author":"Barber P. S.","year":"2024"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202500017","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.202500017","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202500017","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,2,17]],"date-time":"2026-02-17T13:06:45Z","timestamp":1771333605000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202500017"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,6,17]]},"references-count":64,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2025,9]]}},"alternative-id":["10.1002\/asia.202500017"],"URL":"https:\/\/doi.org\/10.1002\/asia.202500017","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,6,17]]},"assertion":[{"value":"2025-01-03","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-06-05","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-06-17","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e00017"}}