{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T11:38:59Z","timestamp":1789731539635,"version":"4.0.1"},"reference-count":52,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2025,7,8]],"date-time":"2025-07-08T00:00:00Z","timestamp":1751932800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,7,8]],"date-time":"2025-07-08T00:00:00Z","timestamp":1751932800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2025,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Herein, we report the synthesis and characterization of highly electron\u2010deficient, air\u2010stable iron(II)porphyrin complex (1) [Fe\n                    <jats:sup>II<\/jats:sup>\n                    (TFPPCl\n                    <jats:sub>8<\/jats:sub>\n                    )(OHMe)\n                    <jats:sub>2<\/jats:sub>\n                    , H\n                    <jats:sub>2<\/jats:sub>\n                    TFPPCl\n                    <jats:sub>8<\/jats:sub>\n                    \u00a0=\u00a0tetrakis(pentafluorophenyl)\u20102,3,7,8,12,13,17,18\u2010octachloroporphyrin, OHMe\u00a0=\u00a0methanol] and its catalytic activity toward olefin aziridination. The addition of highly electron\u2010withdrawing substituents at\n                    <jats:italic>meso<\/jats:italic>\n                    and\n                    <jats:italic>\u03b2<\/jats:italic>\n                    \u2010positions on the periphery of the porphyrin macrocycle significantly distorts its geometric structure, and this modulation impacts its macrocycle properties while enabling the facile isolation of air\u2010stable high\u2010spin Fe(TFPPCl\n                    <jats:sub>8<\/jats:sub>\n                    )(OHMe)\n                    <jats:sub>2<\/jats:sub>\n                    in a highly nonplanar macrocyclic environment. The complex is structurally analyzed through single\u2010crystal X\u2010ray diffraction, and the supramolecular self\u2010assembly was investigated using density functional theory (DFT) and Hirshfeld analysis. Hirshfeld's study reveals the formation of halogen\u2010bonded supramolecular synthons involving fluorine and chlorine atoms on the porphyrin periphery. Catalytic aziridination on olefins was performed under mild conditions, showing that the catalyst is highly active toward aziridine formation under homogeneous conditions. The presence of strong electron\u2010withdrawing substituents (F and Cl) at the porphyrin periphery makes the metal center highly electron\u2010deficient and have high electron affinity, leading to variation in activity for substituted olefins. DFT calculations were performed to investigate the electronic structure of the (Por)Fe\n                    <jats:sup>IV<\/jats:sup>\n                    NTs species, which is an active site during catalysis reaction.\n                  <\/jats:p>","DOI":"10.1002\/asia.202500301","type":"journal-article","created":{"date-parts":[[2025,7,8]],"date-time":"2025-07-08T04:25:45Z","timestamp":1751948745000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis of Highly Electron\u2010Deficient Iron(II)\u2010Porphyrins and Their Catalytic Efficiency for C\u2500N Bond Formation Reactions"],"prefix":"10.1002","volume":"20","author":[{"given":"Swati","family":"Dhamija","sequence":"first","affiliation":[{"name":"Amity Institute of Click Chemistry Research and Studies (AICCRS) Amity University  Noida Uttar Pradesh 201313 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rafia","family":"Siddiqui","sequence":"additional","affiliation":[{"name":"Amity Institute of Click Chemistry Research and Studies (AICCRS) Amity University  Noida Uttar Pradesh 201313 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lovleen","family":"Kaur","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Thapar Institute of Engineering and Technology  Patiala Punjab 147004 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ritam","family":"Das","sequence":"additional","affiliation":[{"name":"Amity Institute of Click Chemistry Research and Studies (AICCRS) Amity University  Noida Uttar Pradesh 201313 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Devalina","family":"Ray","sequence":"additional","affiliation":[{"name":"Amity Institute of Click Chemistry Research and Studies (AICCRS) Amity University  Noida Uttar Pradesh 201313 India"},{"name":"Amity Institute of Biotechnology Amity University  Noida India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Debashish","family":"Mandal","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Thapar Institute of Engineering and Technology  Patiala Punjab 147004 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hatem M.","family":"Titi","sequence":"additional","affiliation":[{"name":"Department of Chemistry McGill University  801 Sherbrooke St. West Montreal QC H3A0B8 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1658-9887","authenticated-orcid":false,"given":"Ranjan","family":"Patra","sequence":"additional","affiliation":[{"name":"Amity Institute of Click Chemistry Research and Studies (AICCRS) Amity University  Noida Uttar Pradesh 201313 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,8]]},"reference":[{"key":"e_1_2_9_1_1","first-page":"167","volume-title":"The Porphyrin Handbook","author":"Shelnutt J. A.","year":"2000"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00391K"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-021-00291-4"},{"key":"e_1_2_9_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b00009"},{"key":"e_1_2_9_3_3","doi-asserted-by":"publisher","DOI":"10.1039\/c0cs00142b"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00644"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature06485"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200601814"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C0CS00070A"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja072219k"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja204800a"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b03765"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c05407"},{"key":"e_1_2_9_12_1","first-page":"2580","volume":"9","author":"Liu Y.","year":"2014","journal-title":"Chem. Asian J."},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201000581"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806059"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c10719"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c01427"},{"key":"e_1_2_9_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC03677B"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c03791"},{"key":"e_1_2_9_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703580"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00082a034"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic300229u"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00527a028"},{"key":"e_1_2_9_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic025869s"},{"key":"e_1_2_9_20_3","doi-asserted-by":"publisher","DOI":"10.1021\/ic026307b"},{"key":"e_1_2_9_20_4","first-page":"m830","volume":"61","author":"Hu C.","year":"2005","journal-title":"Acta Crystallogr."},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213760"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/B203191B"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg400735f"},{"key":"e_1_2_9_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c03791"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CE00333F"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic700827w"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9816741"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol049691k"},{"key":"e_1_2_9_27_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC00784F"},{"key":"e_1_2_9_27_3","doi-asserted-by":"publisher","DOI":"10.1021\/ol402276f"},{"key":"e_1_2_9_27_4","first-page":"148","volume":"248","author":"Yan S. Y.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.464304"},{"key":"e_1_2_9_28_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"e_1_2_9_28_3","doi-asserted-by":"publisher","DOI":"10.1039\/b515623h"},{"key":"e_1_2_9_28_4","first-page":"8699","volume":"113","author":"Weigend F.","year":"2005","journal-title":"J. Chem. Phys."},{"key":"e_1_2_9_28_5","doi-asserted-by":"publisher","DOI":"10.1021\/cr9904009"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c00463"},{"key":"e_1_2_9_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC03505G"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c02283"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200602799"},{"key":"e_1_2_9_31_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC02526J"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b04695"},{"key":"e_1_2_9_33_1","unstructured":"SAINT+ version 6.02 Bruker AXS Madison WI1999."},{"key":"e_1_2_9_34_1","volume-title":"SHELXS Version\u20102018\/3 and SHELXL Version\u20102018\/3: Programs for Crystal Structure Solution and Refinement","author":"Sheldrick G. M.","year":"2018"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889899006020"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202500301","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.202500301","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202500301","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,2,17]],"date-time":"2026-02-17T13:06:51Z","timestamp":1771333611000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202500301"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,7,8]]},"references-count":52,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2025,9]]}},"alternative-id":["10.1002\/asia.202500301"],"URL":"https:\/\/doi.org\/10.1002\/asia.202500301","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,7,8]]},"assertion":[{"value":"2025-02-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-06-26","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e00301"}}