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Attempts to functionalize these complexes by salt metathesis reaction revealed that the chlorido complexes are quite unreactive precursors, whereas the iodo complexes readily engage in a broad variety of reactions. We report the azide complexes (<jats:bold>1\u2010N<jats:sub>3<\/jats:sub><\/jats:bold> and <jats:bold>2\u2010N<jats:sub>3<\/jats:sub><\/jats:bold>) as well as the heavy cyanate complexes with the general formula (PN)<jats:sub>2<\/jats:sub>M(OC<jats:italic>Pn<\/jats:italic>) (M\u00a0=\u00a0Sc; <jats:italic>Pn<\/jats:italic>\u00a0=\u00a0P (<jats:bold>1\u2010OCP<\/jats:bold>), <jats:italic>Pn<\/jats:italic>\u00a0=\u00a0As (1\u2010<jats:bold>OCAs<\/jats:bold>) and M\u00a0=\u00a0Y; <jats:italic>Pn<\/jats:italic>\u00a0=\u00a0P (<jats:bold>2\u2010OCP<\/jats:bold>), <jats:italic>Pn<\/jats:italic>\u00a0=\u00a0As (<jats:bold>2\u2010OCAs<\/jats:bold>)). Furthermore, the amido and phosphanido complexes of the general formula (PN)<jats:sub>2<\/jats:sub>M(<jats:italic>Pn<\/jats:italic>HMesityl) with <jats:italic>Pn<\/jats:italic>\u00a0=\u00a0N (<jats:bold>1\u2010NHMes<\/jats:bold>, <jats:bold>2\u2010NHMes<\/jats:bold>) and <jats:italic>Pn<\/jats:italic>\u00a0=\u00a0P (<jats:bold>1\u2010PHMes<\/jats:bold>, <jats:bold>2\u2010PHMes<\/jats:bold>) are reported. Attempts to synthesize benzyl complexes of the general type (PN)<jats:sub>2<\/jats:sub>M(Benzyl) with M\u00a0=\u00a0Sc, Y, La revealed drastic differences in the reactivity of the group III metal ions. While the scandium and yttrium complexes displayed elimination of KPN without the formation of defined metal complexes, for lanthanum, defined C\u2010H activation chemistry has been observed, yielding \u2010ate complex <jats:bold>3\u2010CH<\/jats:bold>.<\/jats:p>","DOI":"10.1002\/asia.202500364","type":"journal-article","created":{"date-parts":[[2025,4,28]],"date-time":"2025-04-28T05:39:33Z","timestamp":1745818773000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Diverging Reactivity in Anilidophosphine Supported Group III Complexes"],"prefix":"10.1002","volume":"20","author":[{"given":"Florian","family":"Hett","sequence":"first","affiliation":[{"name":"Department of General, Inorganic and Theoretical Chemistry University of Innsbruck  Innrain 80\u201382, 6020 Innsbruck 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Austria"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5353-0801","authenticated-orcid":false,"given":"Stephan","family":"Hohloch","sequence":"additional","affiliation":[{"name":"Department of General, Inorganic and Theoretical Chemistry University of Innsbruck  Innrain 80\u201382, 6020 Innsbruck 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These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service."}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202500364","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T20:11:35Z","timestamp":1759954295000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202500364"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,4,28]]},"references-count":92,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2025,7]]}},"alternative-id":["10.1002\/asia.202500364"],"URL":"https:\/\/doi.org\/10.1002\/asia.202500364","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"type":"print","value":"1861-4728"},{"type":"electronic","value":"1861-471X"}],"subject":[],"published":{"date-parts":[[2025,4,28]]},"assertion":[{"value":"2025-02-28","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-04-01","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-04-28","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202500364"}}