{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T17:02:43Z","timestamp":1789578163333,"version":"build-2803163510"},"reference-count":56,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2025,7,11]],"date-time":"2025-07-11T00:00:00Z","timestamp":1752192000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,7,11]],"date-time":"2025-07-11T00:00:00Z","timestamp":1752192000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2025,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Efficient artificial light\u2010harvesting systems (ALH) involving energy transfer via FRET in an aqueous environment has been reported. Hydrazone ligands\n                    <jats:bold>L1<\/jats:bold>\n                    \u2212\n                    <jats:bold>L3<\/jats:bold>\n                    and \u2010BF\n                    <jats:sub>2<\/jats:sub>\n                    complexes (BODIHYs;\n                    <jats:bold>B1\u2212B3<\/jats:bold>\n                    ) derived from these have been synthesized and meticulously characterized by various techniques like\n                    <jats:sup>1<\/jats:sup>\n                    H,\n                    <jats:sup>13<\/jats:sup>\n                    C,\n                    <jats:sup>11<\/jats:sup>\n                    B,\n                    <jats:sup>19<\/jats:sup>\n                    F NMR, ESI\u2013MS, UV\u2013vis, fluorescence spectroscopy, and structures of\n                    <jats:bold>B1<\/jats:bold>\n                    and\n                    <jats:bold>B2<\/jats:bold>\n                    unequivocally determined by X\u2212ray single crystal analyses. Applicability of the\n                    <jats:bold>B1\u2212B3<\/jats:bold>\n                    have been examined as a LHS platform and categorically shown that these in combination with rhodamine B (RhB) display efficient light harvesting activity under aqueous conditions via aggregation\u2212induced emission (AIE). Calculated energy transfer efficiency and antenna effect for the BODIHYs are significantly high (\n                    <jats:bold>B1<\/jats:bold>\n                    =\u00a022%, 5.04;\n                    <jats:bold>B2<\/jats:bold>\n                    =\u00a018%, 4.07) at a donor\/acceptor ratio of 23:1. Furthermore, hypsochromic shift shown by\n                    <jats:bold>B1<\/jats:bold>\n                    and\n                    <jats:bold>B2<\/jats:bold>\n                    after grinding completely reverses upon exposure to dichloromethane vapors. Powder X\u2212ray diffraction (PXRD) analyses before and after grinding revealed that the external forces modify crystal packing by disrupting weak intra\u2212\u00a0and intermolecular interactions within the molecules.\n                  <\/jats:p>","DOI":"10.1002\/asia.202500434","type":"journal-article","created":{"date-parts":[[2025,7,11]],"date-time":"2025-07-11T10:45:15Z","timestamp":1752230715000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["AIE\u2212Active BODIHYs Based on Benzothiazole\u2013Hydrazone Chelates and Their Artificial Light Harvesting and Reversible Mechanochromic Behavior"],"prefix":"10.1002","volume":"20","author":[{"given":"Nikhil Kumar","family":"Singh","sequence":"first","affiliation":[{"name":"Department of Chemistry Institute of Science Banaras Hindu University  Varanasi Uttar Pradesh 221005 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ashish Kumar","family":"Kushwaha","sequence":"additional","affiliation":[{"name":"Department of Chemistry Institute of Science Banaras Hindu University  Varanasi Uttar Pradesh 221005 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9454-1929","authenticated-orcid":false,"given":"Daya Shankar","family":"Pandey","sequence":"additional","affiliation":[{"name":"Department of Chemistry Institute of Science Banaras Hindu University  Varanasi Uttar Pradesh 221005 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,11]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/374517a0"},{"key":"e_1_2_9_2_1","first-page":"5531","volume":"5","author":"Melis A.","year":"2012","journal-title":"EES"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar950110o"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1145"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/B802262N"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchembio.1555"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00002"},{"key":"e_1_2_9_8_1","first-page":"39","volume":"258","author":"You C.\u2010C.","year":"2005","journal-title":"J. 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