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However, the practical application of VFB systems is hindered by the poor thermal stability of vanadium electrolytes under extreme temperatures, where precipitation occurs at high temperatures (\u226540\u00a0\u00b0C) and low temperatures (\u226410\u00a0\u00b0C), severely limiting their geographical adaptability. This study proposes a wide\u2010temperature\u2010range (WTR) electrolyte by introducing four organic\/inorganic additives, comprising benzene sulfonate, phosphate salts, halide salts, and imidazole into the conventional vanadium electrolyte. The operational temperature of vanadium electrolyte was extended to \u20105\u223c45\u00a0\u00b0C. Electrochemical characterization confirmed that WTR\u2010electrolyte has comparable performance to the conventional electrolyte at 100\u00a0mA cm<jats:sup>\u22122<\/jats:sup>, while not sacrificing performance. Furthermore, the WTR\u2010electrolyte can not only be stored in the temperature range of \u22125\u223c45\u00a0\u00b0C, but also can stably operate at \u22125\u00a0\u00b0C and 45\u00a0\u00b0C. This work provides a viable strategy for designing WTR vanadium electrolytes, offering critical insights to advance the deployment of vanadium\u2010based energy storage systems in diverse climatic environments.<\/jats:p>","DOI":"10.1002\/asia.202500607","type":"journal-article","created":{"date-parts":[[2025,6,12]],"date-time":"2025-06-12T10:59:23Z","timestamp":1749725963000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["A Wide\u2010Temperature\u2010Range Electrolyte for all Vanadium Flow Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Jingyu","family":"Zhai","sequence":"first","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites Beijing Key Laboratory of Intelligent Design and Manufacturing for Hydrogen Energy Materials Beijing University of Chemical Technology  Beijing 100029 P. R. 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