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This complex forms a 3D layered structure via assorted intra\u2010layer and inter\u2010layer hydrogen bonds. Functioning as a heterogeneous catalyst,\n                    <jats:bold>Co\u2010L<\/jats:bold>\n                    efficiently promotes the base\u2010free transfer hydrogenation of carbonyl and imine compounds, while using environmentally benign isopropanol as a hydrogen donor. The\n                    <jats:bold>Co\u2010L<\/jats:bold>\n                    illustrates remarkable catalytic activity across diverse substrates, including aldehydes, ketones, and imines, achieving high conversions and exclusive selectivity. The biomass\u2010derived substrates, such as furfural, levulinic acid, and 5\u2010methylfurfural, along with pharmaceutically significant ones, such as cinnamaldehyde and estrone, were effectively transformed to their target products. The mechanistic studies revealed a synergy between the Lewis acid\u2013base pairs (Co\n                    <jats:sup>2+<\/jats:sup>\n                    \/OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) and Br\u00f8nsted acid sites (\u2010COOH) during the catalysis. A combination of spectral and molecular docking studies asserts the role of dual functionalities in\n                    <jats:bold>Co\u2010L<\/jats:bold>\n                    . An ester analogue of\n                    <jats:bold>Co\u2010L<\/jats:bold>\n                    ,\n                    <jats:bold>\n                      <jats:sup>Et<\/jats:sup>\n                      Co\u2010L\n                    <\/jats:bold>\n                    , showed lower catalytic activity, asserting the role of Br\u00f8nsted acidic groups.\n                  <\/jats:p>","DOI":"10.1002\/asia.202500772","type":"journal-article","created":{"date-parts":[[2025,8,10]],"date-time":"2025-08-10T05:45:37Z","timestamp":1754804737000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Transfer Hydrogenation Catalyzed by a Bifunctional Cobalt\u2010Based Supramolecular Complex Offering Hydrogen Bonding Cavities"],"prefix":"10.1002","volume":"20","author":[{"given":"Divya","family":"Goyal","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Delhi, North Campus  Delhi 110007 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kusum","family":"Boora","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Delhi, North Campus  Delhi 110007 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"family":"Aashish","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Delhi, North Campus  Delhi 110007 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"family":"Meenakshi","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Delhi, North Campus  Delhi 110007 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2454-6705","authenticated-orcid":false,"given":"Rajeev","family":"Gupta","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Delhi, North Campus  Delhi 110007 India"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,8,9]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c04939"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0957-4166(99)00216-5"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.200800196"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b04331"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00334J"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc12326b"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc45900d"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201206051"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1dt10544b"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2004.04.007"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja211658t"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal8120671"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2014.04.018"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201300978"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.4c05479"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201900358"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.202400338"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201705423"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2022.10.022"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol401560q"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b05613"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201801334"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr4002269"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.1c06956"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c04786"},{"key":"e_1_2_9_26_1","first-page":"285","volume-title":"Ullmann's Encyclopedia of Industrial Chemistry","author":"Hoydonckx H. 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