{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T01:01:41Z","timestamp":1786496501555,"version":"build-2736575974"},"reference-count":38,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2025,12,9]],"date-time":"2025-12-09T00:00:00Z","timestamp":1765238400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,12,9]],"date-time":"2025-12-09T00:00:00Z","timestamp":1765238400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U23A20593"],"award-info":[{"award-number":["U23A20593"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22171151"],"award-info":[{"award-number":["22171151"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004763","name":"Natural Science Foundation of Inner Mongolia Autonomous Region","doi-asserted-by":"publisher","award":["2021MS02004"],"award-info":[{"award-number":["2021MS02004"]}],"id":[{"id":"10.13039\/501100004763","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2026,1]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Chiral trivalent lanthanide complexes are of interest since their parity\u2010allowed magnetic dipole transition generally shows large luminescence dissymmetry (\n                    <jats:italic>g<\/jats:italic>\n                    <jats:sub>lum<\/jats:sub>\n                    ) factors. However, the luminescence intensity is normally weak, which is yet another challenge. Herein, we introduce electron\u2010withdrawing and \u2010donating moieties (F and methyl, respectively) at the para\u2010positions of phenyl on N,N'\u2010bis (1\u2010phenylethyl)\u20102,6\u2010pyridinediamide. We found that this approach, for example, modifying the remote positions of ligands, enables decreasing the triplet state energy levels of ligands from 27060\u00a0cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    (H) to 24154\u00a0cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    (F) and 24390\u00a0cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    (methyl) and enhancing the ligand\u2010to\u2010ion sensitization from 0.35 to 0.41 and 0.47 and photoluminescent quantum yields (PLQYs) from 17% to 23% and 25%. The\n                    <jats:italic>g<\/jats:italic>\n                    <jats:sub>lum<\/jats:sub>\n                    \u2010factors are \u00b10.1 for the three Tb(III) complexes coordinated with the synthesized ligands in their ethanol solutions, yielding circularly polarized luminescence (CPL) brightness (B) values of 0.017, 0.023, and 0.025, respectively. Single crystal structures reveal the chirality transfer from the chiral ligands to the complex and then to supramolecular chiral packing of complexes and also effective modulations on the supramolecular chiral packing. Collectively, these findings establish remote ligand engineering as a robust and versatile strategy for fine\u2010tuning CPL brightness.\n                  <\/jats:p>","DOI":"10.1002\/asia.202500854","type":"journal-article","created":{"date-parts":[[2025,12,10]],"date-time":"2025-12-10T04:14:01Z","timestamp":1765340041000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Enhancing Circularly Polarized Luminescence of Tb(III) Complexes via Remote Substitutions on Pyridine\u20102,6\u2010Dicarboxamide"],"prefix":"10.1002","volume":"21","author":[{"given":"Yanbo","family":"Zhao","sequence":"first","affiliation":[{"name":"Key Laboratory of Advanced Materials Chemistry and Devices (AMCDlab) of the Department of Education of Inner Mongolia Autonomous Region College of Chemistry and Environmental Science Inner Mongolia Normal University  Zhaowuda Road, No 81 Hohhot 010022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongnan","family":"Tu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Advanced Materials Chemistry and Devices (AMCDlab) of the Department of Education of Inner Mongolia Autonomous Region College of Chemistry and Environmental Science Inner Mongolia Normal University  Zhaowuda Road, No 81 Hohhot 010022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruiyan","family":"Dai","sequence":"additional","affiliation":[{"name":"Key Laboratory of Advanced Materials Chemistry and Devices (AMCDlab) of the Department of Education of Inner Mongolia Autonomous Region College of Chemistry and Environmental Science Inner Mongolia Normal University  Zhaowuda Road, No 81 Hohhot 010022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander A.","family":"Trifonov","sequence":"additional","affiliation":[{"name":"A.N. Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences  28 Vavilova Street Moscow 119334 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuanlang","family":"Zhan","sequence":"additional","affiliation":[{"name":"Key Laboratory of Advanced Materials Chemistry and Devices (AMCDlab) of the Department of Education of Inner Mongolia Autonomous Region College of Chemistry and Environmental Science Inner Mongolia Normal University  Zhaowuda Road, No 81 Hohhot 010022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,12,9]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5b03386"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC04289J"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b07005"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC03032H"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC05198K"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT03615B"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC06909G"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8NA00216A"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201903200"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.1c00864"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.0c02013"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.8b00112"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b00986"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07178"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT03576A"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b01480"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT00699H"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC06568D"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202307448"},{"issue":"18","key":"e_1_2_8_21_1","first-page":"2655","article-title":"Lanthanide Triple Helical Complexes With a Chiral Ligand Derived From 2,6\u2010Pyridinedicarboxylic Acid","volume":"2001","author":"Muller G.","year":"2001","journal-title":"Journal of the Chemical Society"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/chir.20476"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc11326g"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201106863"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.3390\/inorganics9100074"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TC01044H"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC08362H"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT02753F"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT00062K"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT01808A"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1071\/ch20074"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c00058"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010017\u201001025\u20101"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b03972"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b02764"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/c001780a"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr010452"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC05009J"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5FD00105F"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202500854","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.202500854","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202500854","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,24]],"date-time":"2026-07-24T04:06:25Z","timestamp":1784865985000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202500854"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,12,9]]},"references-count":38,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2026,1]]}},"alternative-id":["10.1002\/asia.202500854"],"URL":"https:\/\/doi.org\/10.1002\/asia.202500854","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,12,9]]},"assertion":[{"value":"2025-08-09","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-11-20","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-12-09","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e00854"}}