{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,30]],"date-time":"2026-04-30T20:06:55Z","timestamp":1777579615853,"version":"3.51.4"},"reference-count":48,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2026,1,18]],"date-time":"2026-01-18T00:00:00Z","timestamp":1768694400000},"content-version":"vor","delay-in-days":17,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,1]],"date-time":"2026-01-01T00:00:00Z","timestamp":1767225600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2026,1]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    This work reports on the discovery of new materials in the Sc\n                    <jats:sub>2\u2010x\u2010y<\/jats:sub>\n                    Fe\n                    <jats:sub>x<\/jats:sub>\n                    Al\n                    <jats:sub>y<\/jats:sub>\n                    W\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>12<\/jats:sub>\n                    family. Members with compositions containing high concentrations of Fe are found to crystallize to a structure in the monoclinic\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>a<\/jats:italic>\n                    symmetry, while compositions with low values of Fe and Al crystallize in the orthorhombic\n                    <jats:italic>Pnca<\/jats:italic>\n                    structure at room temperature. The orthorhombic samples in the compositional range x = 0.5, y \u2264 0.5 are found to transition to the monoclinic\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>a<\/jats:italic>\n                    structure at 210\u2013230 K. Specifically, Sc\n                    <jats:sub>1.25<\/jats:sub>\n                    Fe\n                    <jats:sub>0.5<\/jats:sub>\n                    Al\n                    <jats:sub>0.25<\/jats:sub>\n                    W\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>12<\/jats:sub>\n                    is found to exhibit a volumetric coefficient of thermal expansion (CTE) of \u22120.48(7) \u00d7 10\n                    <jats:sup>\u22126<\/jats:sup>\n                    K\n                    <jats:sup>\u22121<\/jats:sup>\n                    over the range 300\u20131000 K, a near\u2010zero thermal expansion material\u2014this CTE value is lower than precision invar variants and it is persistent over seven times the temperature range. Increasing the Al concentration to y = 0.75 increases the CTE to 4.69(8) \u00d7 10\n                    <jats:sup>\u22126<\/jats:sup>\n                    K\n                    <jats:sup>\u22121<\/jats:sup>\n                    over the range 300\u20131000 K and decreasing it to y = 0 decreases the CTE to \u22124.22(6) \u00d7 10\u20136 K\n                    <jats:sup>\u22121<\/jats:sup>\n                    over the range 300\u20131000 K. This work probes the phase\u2010space with an intention to correlate doping regimes to the physical property of volume change.\n                  <\/jats:p>","DOI":"10.1002\/asia.202500979","type":"journal-article","created":{"date-parts":[[2026,1,19]],"date-time":"2026-01-19T04:05:27Z","timestamp":1768795527000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Phase Diagram and Compositional Studies of Sc\n                    <sub>2\u2010x\u2010y<\/sub>\n                    Fe\n                    <sub>x<\/sub>\n                    Al\n                    <sub>y<\/sub>\n                    W\n                    <sub>3<\/sub>\n                    O\n                    <sub>12<\/sub>\n                    : Discovery of New Zero and Low Thermal Expansion Materials"],"prefix":"10.1002","volume":"21","author":[{"given":"Liam J.","family":"McKinlay","sequence":"first","affiliation":[{"name":"School of Chemistry University of New South Wales  Sydney NSW Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Helen E.","family":"Maynard\u2010Casely","sequence":"additional","affiliation":[{"name":"Australian Centre for Neutron Scattering Australian Nuclear Science and Technology Organisation (ANSTO)  Lucas Heights NSW Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Helen E. 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