{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T22:41:14Z","timestamp":1790203274980,"version":"4.1.0"},"reference-count":50,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2025,6,27]],"date-time":"2025-06-27T00:00:00Z","timestamp":1750982400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,6,27]],"date-time":"2025-06-27T00:00:00Z","timestamp":1750982400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2025,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Nitroaromatic compounds are widely used in various industries, including dye manufacturing, leather processing, plastics, fungicides, pesticides, insecticides, pharmaceuticals, and paper production. However, specific nitrophenols such as para\u2010nitrophenol are recognized as hazardous environmental pollutants. Therefore, their removal or conversion into less harmful compounds, such as 4\u2010aminophenol is of paramount importance. In this study, a copper\u2010based metal\u2013organic framework (Cu\u2010BDC MOF) was synthesized via a simple, cost\u2010effective hydrothermal method at different deposition temperatures. The synthesized materials were characterized using techniques such as X\u2010ray diffraction (XRD), Raman spectroscopy, X\u2010ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The Cu\u2010BDC MOF, which exhibited a square plate\u2010like morphology served as an efficient catalyst for the reduction of 4\u2010nitrophenol to 4\u2010aminophenol. Sodium borohydride (NaBH\u2084) was employed as the reducing agent in conjunction with the Cu\u2010MOF catalyst. An increase in the concentration of NaBH\u2084 enhanced the catalytic performance by supplying more BH\u2084\n                    <jats:sup>\u2212<\/jats:sup>\n                    ions, which act as electron donors in the reduction reaction. The 4\u2010NP reduction reaction follows a Langmuir\u2010Hinshelwood mechanism and demonstrates apparent pseudo\u2010first\u2010order kinetics, indicating the reaction proceeds via adsorption of both reactants on the catalyst surface followed by surface\u2010mediated electron transfer.\n                  <\/jats:p>","DOI":"10.1002\/asia.70119","type":"journal-article","created":{"date-parts":[[2025,6,27]],"date-time":"2025-06-27T04:54:47Z","timestamp":1751000087000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Catalytic Activity of Cu\u2010MOF Catalyst for 4\u2010Nitrophenol Reduction"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7204-844X","authenticated-orcid":false,"given":"Yuvaraj M.","family":"Hunge","sequence":"first","affiliation":[{"name":"Research Center for Space System Innovation, Research Institute for Science and Technology Tokyo University of Science  Yamazaki Noda Chiba 278\u20138510 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"A. 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