{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T17:27:51Z","timestamp":1784827671081,"version":"3.55.0"},"reference-count":63,"publisher":"Wiley","issue":"22","license":[{"start":{"date-parts":[[2025,9,15]],"date-time":"2025-09-15T00:00:00Z","timestamp":1757894400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2025,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    In this study, we employed a simple and efficient method to synthesize two porous covalent triazine frameworks (CTFs) using a cyanuric chloride core with both 1,4\u2010diaminobenzene and 1,1\u2035\u2010biphenyl\u20104,4\u2035\u2010diamine, which were subsequently embedded with copper acetate, giving Cu@CTF electrocatalysts. The composite materials were comprehensively characterized, and their performance in the electrochemical CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR) was systematically evaluated. The Cu@CTFs exhibited significant enhancements in CO\n                    <jats:sub>2<\/jats:sub>\n                    RR performance compared to their unmodified counterparts. The as\u2010synthesized Cu@CC\u2010BP\u2010CTF electrocatalyst possessed exceptional catalytic efficiency due to its highly porous structure and great surface area. At a voltage of 1.6\u00a0V versus RHE, it achieved a maximum CO Faradaic efficiency of 39%. In addition, the activity of this system was characterized by a partial current density of around 85.8 mAcm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in a flow\u2010cell configuration. Furthermore, this catalyst demonstrated remarkable stability over 10\u00a0h, highlighting its significant potential for real\u2010world utilization in CO\n                    <jats:sub>2<\/jats:sub>\n                    RR. The Cu@CC\u2010BP\u2010CTF electrode exhibited superior CO\n                    <jats:sub>2<\/jats:sub>\n                    RR activity, higher mass activity, and improved charge transfer rates incomparable to the unmodified counterpart. These findings highlight the crucial role of copper in modifying the surface properties of electrocatalysts, providing valuable insights into the design strategies for advanced materials with enhanced performance in electrochemical applications.\n                  <\/jats:p>","DOI":"10.1002\/asia.70292","type":"journal-article","created":{"date-parts":[[2025,9,15]],"date-time":"2025-09-15T13:36:37Z","timestamp":1757943397000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Engineering of Copper\u2010Based Nitrogen\u2010Rich Covalent Triazine Frameworks (Cu@CTFs) as Highly Efficient Electrocatalysts for Carbon Dioxide Reduction"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7919-0748","authenticated-orcid":false,"given":"Ahmed F.","family":"Saber","sequence":"first","affiliation":[{"name":"Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management (IRC\u2010HTCM) King Fahd University of Petroleum &amp; Minerals  Dhahran 31261 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Munzir H.","family":"Suliman","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management (IRC\u2010HTCM) King Fahd University of Petroleum &amp; Minerals  Dhahran 31261 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ali M.","family":"Tayeb","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management (IRC\u2010HTCM) King Fahd University of Petroleum &amp; Minerals  Dhahran 31261 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohamed","family":"Essalhi","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management (IRC\u2010HTCM) King Fahd University of Petroleum &amp; Minerals  Dhahran 31261 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohamed Hammad","family":"Elsayed","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management (IRC\u2010HTCM) King Fahd University of Petroleum &amp; Minerals  Dhahran 31261 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amr","family":"Sabbah","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management (IRC\u2010HTCM) King Fahd University of Petroleum &amp; Minerals  Dhahran 31261 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kuei\u2010Hsien","family":"Chen","sequence":"additional","affiliation":[{"name":"Center for Condensed Matter Sciences National Taiwan University  Taipei 10617 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mahmoud M.","family":"Abdelnaby","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management (IRC\u2010HTCM) King Fahd University of Petroleum &amp; Minerals  Dhahran 31261 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9,15]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enpol.2012.10.046"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2020.104756"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00025F"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2021.131646"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ee41272e"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.5c00012"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.9b02519"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.5c00992"},{"key":"e_1_2_8_9_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2022.137158","volume":"446","author":"Samy M. M.","year":"2022","journal-title":"J. Chem. Eng."},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.reactfunctpolym.2025.106286"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.165892"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coche.2013.03.005"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0306-7"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-019-0450-y"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature19060"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2019.06.002"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.8b00474"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1224581"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aax4608"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature16455"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja2108799"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201701809"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2ee21234j"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2018.05.001"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2016.04.009"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00705"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs500537y"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0201-7"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms12123"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-017-0009-x"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aas9100"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02124"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-05544-3"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201802083"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr300463y"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c04714"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/cey2.87"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2016.06.172"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201705512"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202100090"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.2c00326"},{"key":"e_1_2_8_42_1","doi-asserted-by":"crossref","DOI":"10.1002\/ange.202200003","volume":"134","author":"Lu M.","year":"2022","journal-title":"Angew. Chem., Int. Ed."},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201601387"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213388"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201703646"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119174"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA12442F"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC01171C"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm802981m"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b01320"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4017842"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06640"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ee41444b"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2022.153481"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.2c03154"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b07644"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b14743"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.6b16769"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja204728y"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja206846p"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402365"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.133900"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.117915"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.70292","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,18]],"date-time":"2025-11-18T08:57:30Z","timestamp":1763456250000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.70292"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9,15]]},"references-count":63,"journal-issue":{"issue":"22","published-print":{"date-parts":[[2025,11]]}},"alternative-id":["10.1002\/asia.70292"],"URL":"https:\/\/doi.org\/10.1002\/asia.70292","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9,15]]},"assertion":[{"value":"2025-07-01","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-08-21","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-15","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70292"}}