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However, high temperature and\/or high pressure are required for traditional thermally driven cycloaddition of CO\n                    <jats:sub>2<\/jats:sub>\n                    with aziridines by employing so\u2010far reported catalysts, and more efficient catalysts need to be developed for mild procedures. Herein, we construct three zinc porphyrin\u2010based covalent triazine frameworks (ZnDBP\u2010CTFs), including ZnHDBP\u2010CTF and halogen\u2010substituted ZnDBP\u2010CTFs (ZnClDBP\u2010CTF and ZnBrDBP\u2010CTF) at porphyrin meso positions, and investigate their catalytic activity in CO\n                    <jats:sub>2<\/jats:sub>\n                    cycloaddition to aziridines. Interestingly, different electron\u2010withdrawing halogen atoms in the ZnDBP\u2010CTFs skeleton not only tune the Lewis acidity of the coordinated zinc center but also vary the BET surface area of the materials. Encouragingly, under mild conditions (1 atm CO\n                    <jats:sub>2<\/jats:sub>\n                    , 70\u00b0C), the ZnBrDBP\u2010CTF with bromine atoms substituted at meso positions of porphyrin rings exhibits remarkable catalytic performance with the reaction rate reaching 16.35\u00a0mol mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which is among the state\u2010of\u2010the\u2010art cases for catalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    cycloaddition to aziridines. This study demonstrates that ZnDBP\u2010CTFs can be rationally tuned by incorporating various halogen atoms at the meso positions of the porphyrin units, thereby providing a robust strategy for modulating the catalytic activity of metalloporphyrin\u2010based CTFs.\n                  <\/jats:p>","DOI":"10.1002\/asia.70416","type":"journal-article","created":{"date-parts":[[2025,11,6]],"date-time":"2025-11-06T04:38:11Z","timestamp":1762403891000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Halogen\u2010Substituted Zinc Porphyrin\u2010Based Covalent Triazine Frameworks for Efficient Catalytic CO\n                    <sub>2<\/sub>\n                    Cycloaddition to Aziridines"],"prefix":"10.1002","volume":"20","author":[{"given":"Ji","family":"Xiong","sequence":"first","affiliation":[{"name":"School of Chemical Engineering &amp; Technology Tianjin University  Tianjin PR China"},{"name":"Tianjin Collaborative 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