{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,12]],"date-time":"2026-02-12T16:40:06Z","timestamp":1770914406663,"version":"3.50.1"},"reference-count":69,"publisher":"Wiley","issue":"24","license":[{"start":{"date-parts":[[2025,12,3]],"date-time":"2025-12-03T00:00:00Z","timestamp":1764720000000},"content-version":"vor","delay-in-days":2,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,12,1]],"date-time":"2025-12-01T00:00:00Z","timestamp":1764547200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21603004"],"award-info":[{"award-number":["21603004"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2025,12]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Electrocatalytic oxidation of biomass molecules such as ethanol in hybrid alkaline water electrolysis is more thermodynamically favorable and techno\u2010economic attractive to replace conventional pure water electrooxidation to produce green hydrogen. Herein, the flexible and binder\u2010free hollow microtube catalyst arrays of CoS\n                    <jats:sub>2<\/jats:sub>\n                    \/CC, Ni\n                    <jats:sub>0.04<\/jats:sub>\n                    Co\n                    <jats:sub>0.96<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    \/CC, Fe\n                    <jats:sub>0.07<\/jats:sub>\n                    Ni\n                    <jats:sub>0.04<\/jats:sub>\n                    Co\n                    <jats:sub>0.89<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    \/CC, and Fe\n                    <jats:sub>0.08<\/jats:sub>\n                    Ni\n                    <jats:sub>0.10<\/jats:sub>\n                    Co\n                    <jats:sub>0.82<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    \/CC were derived from metal\u2010organic framework arrays anchored on carbon cloth (CC). These arrays exhibited favorable performance in electrochemical water oxidation, ethanol oxidation, and hydrogen evolution processes, because of their obvious advantages in high conductivity and long\u2010term stability. The optimized self\u2010supporting Fe\n                    <jats:sub>0.08<\/jats:sub>\n                    Ni\n                    <jats:sub>0.10<\/jats:sub>\n                    Co\n                    <jats:sub>0.82<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    \/CC electrode composed of a 3D hollow porous microtube structure only needs a low potential of 1.412 and 1.267\u00a0V (vs. RHE) to deliver 10\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    current density for alkaline water and ethanol oxidation reactions, respectively. Simultaneously, the pure CoS\n                    <jats:sub>2<\/jats:sub>\n                    \/CC electrode presents excellent alkaline hydrogen production property among the series self\u2010supporting electrodes with a low overpotential of 188\u00a0mV at 10\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . In this work, it is proved that the hybrid water splitting system, using Fe\n                    <jats:sub>0.08<\/jats:sub>\n                    Ni\n                    <jats:sub>0.10<\/jats:sub>\n                    Co\n                    <jats:sub>0.82<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    \/CC and CoS\n                    <jats:sub>2<\/jats:sub>\n                    \/CC as anode and cathode, respectively, can effectively reduce the cell voltage to 1.479\u00a0V to deliver 10\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    with high pure hydrogen generation and high valued potassium acetate generation.\n                  <\/jats:p>","DOI":"10.1002\/asia.70484","type":"journal-article","created":{"date-parts":[[2025,12,4]],"date-time":"2025-12-04T03:42:52Z","timestamp":1764819772000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Self\u2010Supporting Fe, Ni\u2010Codoped CoS\n                    <sub>2<\/sub>\n                    Hollow Microtube Arrays Electrode as an Effective Catalyst for Alkaline Ethanol\u2010Assisted Overall Water Splitting"],"prefix":"10.1002","volume":"20","author":[{"given":"Jingchao","family":"Zhang","sequence":"first","affiliation":[{"name":"Henan Key Laboratory of New Optoelectronic Functional Materials College of Chemistry and Chemical Engineering Anyang Normal University  Anyang China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiangtao","family":"Kong","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of New Optoelectronic Functional Materials College of Chemistry and Chemical Engineering Anyang Normal University  Anyang China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yucong","family":"Pan","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of New Optoelectronic Functional Materials College of Chemistry and Chemical Engineering Anyang Normal University  Anyang China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zixin","family":"Zhou","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of New Optoelectronic Functional Materials College of Chemistry and Chemical Engineering Anyang Normal University  Anyang China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fujing","family":"Zhao","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of New Optoelectronic Functional Materials College of Chemistry and Chemical Engineering Anyang Normal University  Anyang China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiangwei","family":"Guo","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of New Optoelectronic Functional Materials College of Chemistry and Chemical Engineering Anyang Normal University  Anyang China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Renchun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of New Optoelectronic Functional Materials College of Chemistry and Chemical Engineering Anyang Normal University  Anyang China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Daojun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of New Optoelectronic Functional Materials College of Chemistry and Chemical Engineering Anyang Normal University  Anyang China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6805-2283","authenticated-orcid":false,"given":"Haiqing","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute For Advanced Interdisciplinary Research (iAIR) College of Chemistry and Chemical Engineering University of Jinan  Jinan China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2487-4250","authenticated-orcid":false,"given":"Zhicheng","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemistry School of Science Tianjin Key Laboratory of Molecular Optoelectronic Sciences Tianjin University  Tianjin P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,12,3]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE02467A"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA01931D"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202203568"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202316449"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE01816K"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/smm2.1117"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2024.06.045"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2023.03.242"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c15365"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.4c05299"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4QI00629A"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC02263C"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2405846121"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.12409"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40843\u2010020\u20101524\u20105"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2023.130930"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2021.11.115"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2025.137876"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202414628"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.2c04570"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202001434"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202509741"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202507951"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202507609"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC05071D"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10562\u2010022\u201004014\u20102"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2TA02493D"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202101312"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QM00089C"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/celc.201900481"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c09161"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202005436"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT00319D"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QI00902E"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/smm2.1281"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201704681"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c15975"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA00777C"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA03113F"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0NR02058C"},{"key":"e_1_2_9_42_1","article-title":"Microwave\u2010Assisted Synthesis of Cu\/Co\u2010Based Nanoheterostructures for High\u2010Efficiency Alcohol Oxidation","volume":"12","author":"Zhang X. S.","year":"2025","journal-title":"Advancement of Science"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/smm2.1206"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202303614"},{"key":"e_1_2_9_45_1","article-title":"Design and Synthesis of Hollow Nanostructures for Electrochemical Water Splitting","volume":"9","author":"Yang M.","year":"2022","journal-title":"Advancement of Science"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja504099w"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5QI00011D"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.202100735"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7NR06001G"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA09423D"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274\u2010020\u20102807\u20108"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202509007"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00339\u2010021\u201004614\u20106"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201800935"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.2c02055"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC02075D"},{"key":"e_1_2_9_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122388"},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QI00885A"},{"key":"e_1_2_9_59_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2NH00431C"},{"key":"e_1_2_9_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201606585"},{"key":"e_1_2_9_61_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2NJ00773H"},{"key":"e_1_2_9_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c00455"},{"key":"e_1_2_9_63_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201045702\u20104"},{"key":"e_1_2_9_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.5c00618"},{"key":"e_1_2_9_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872\u20102067(25)64727\u20109"},{"key":"e_1_2_9_66_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3DT01892J"},{"key":"e_1_2_9_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2021.06.001"},{"key":"e_1_2_9_68_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2024.160553"},{"key":"e_1_2_9_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c13864"},{"key":"e_1_2_9_70_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c20554"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.70484","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.70484","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.70484","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,2,12]],"date-time":"2026-02-12T15:58:30Z","timestamp":1770911910000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.70484"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,12]]},"references-count":69,"journal-issue":{"issue":"24","published-print":{"date-parts":[[2025,12]]}},"alternative-id":["10.1002\/asia.70484"],"URL":"https:\/\/doi.org\/10.1002\/asia.70484","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,12]]},"assertion":[{"value":"2025-06-27","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-11-21","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-12-03","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70484"}}