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Among these, NH\n                    <jats:sub>3<\/jats:sub>\n                    is particularly significant due to its large\u2010scale industrial synthesis via the Haber\u2013Bosch process. Herein, we report the design of an efficient NO\n                    <jats:sub>3<\/jats:sub>\n                    RR catalyst prepared through a simple synthesis route. Fe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    clusters (2\u20135\u00a0nm) were uniformly deposited on iron phthalocyanine (FePc)\u2010modified N\u2010doped carbon nanotubes (Fe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    \/FePc\/CNT), yielding a high NH\n                    <jats:sub>3<\/jats:sub>\n                    production rate of 58.67\u00a0mg\u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    with a Faradaic efficiency (FE) of 81.89% at \u22121.0\u00a0V versus RHE. Comparative studies with FePc\/CNT, Pc\/CNT, and Fe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    \/CNT confirmed the synergistic effect between Fe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    clusters and FePc, with the optimized Fe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    \/FePc\/CNT catalyst showing superior activity and selectivity. Furthermore, the optimized catalyst exhibited excellent stability for 24\u00a0h. A possible mechanism for NH\n                    <jats:sub>3<\/jats:sub>\n                    formation is proposed on the basis of the reaction intermediates identified by ex situ FTIR and x\u2010ray photoelectron spectroscopy (XPS) analyses.\n                  <\/jats:p>","DOI":"10.1002\/asia.70496","type":"journal-article","created":{"date-parts":[[2025,12,10]],"date-time":"2025-12-10T04:20:19Z","timestamp":1765340419000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Synergistic Effects of Fe\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    Clusters and Iron Phthalocyanine on Carbon Nanotubes for Enhanced Electrochemical Nitrate Reduction"],"prefix":"10.1002","volume":"21","author":[{"given":"Ningma Dorzi","family":"Sherpa","sequence":"first","affiliation":[{"name":"Department of Chemistry University of North Bengal  Darjeeling West Bengal India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hiren","family":"Jungi","sequence":"additional","affiliation":[{"name":"Inorganic Materials and Catalysis Division CSIR\u2010Central Salt &amp; Marine Chemicals Research Institute  Bhavnagar Gujarat India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shakil Ahammad","family":"Chowdhury","sequence":"additional","affiliation":[{"name":"Materials Science Centre Indian Institute of Technology, Kharagpur  Kharagpur West Bengal India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pranay Chandra","family":"Mandal","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of North Bengal  Darjeeling West Bengal India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6763-0301","authenticated-orcid":false,"given":"Nitish","family":"Roy","sequence":"additional","affiliation":[{"name":"Department of Chemistry University 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