{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,11]],"date-time":"2026-04-11T03:49:38Z","timestamp":1775879378541,"version":"3.50.1"},"reference-count":49,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2026,2,2]],"date-time":"2026-02-02T00:00:00Z","timestamp":1769990400000},"content-version":"vor","delay-in-days":1,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,1]],"date-time":"2026-02-01T00:00:00Z","timestamp":1769904000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Electrocatalysis is an efficient method for reducing greenhouse gas emissions and producing high\u2010value chemicals. Metal\u2010organic materials are currently popular materials to improve the catalytic performance of the electrocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR), but due to their inherent conductivity and poor internal active sites, direct application is challenging. Halogens have potential advantages in regulating the activity of carbon dioxide reduction reactions, but they have not yet been directly applied in the practical use of Cd\u2010based electrocatalysts. In this paper, Cd\u20101,3,5\u2010benzenetricarboxylic acid (Cd\u2010BTC) was prepared by the solvothermal method, and halogen atoms were introduced into Cd\u2010BTC materials to obtain halogen\u2010containing X\u2010Cd\u2010BTC (X = F, Cl, Br, and I) catalysts. Their electrocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    RR activity changed significantly with the electronegativity of halogen. Among them, the CO faradaic efficiency (FE\n                    <jats:sub>CO<\/jats:sub>\n                    ) of the best Cl\u2010Cd\u2010BTC catalyst was as high as 97.2% at the potential of \u22121.3\u00a0V versus reversible hydrogen electrode (vs. RHE), and the FE\n                    <jats:sub>CO<\/jats:sub>\n                    remained above 93% after 25,200 s stability test. It showed that the introduction of halogen Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    will lead to strong electronic interaction between Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    and Cd\n                    <jats:sup>2+<\/jats:sup>\n                    , which will accelerate the reaction kinetics, thus significantly improving the electrocatalytic efficiency of Cd\u2010BTC. This catalyst is expected to efficient electrochemical CO\n                    <jats:sub>2<\/jats:sub>\n                    to CO.\n                  <\/jats:p>","DOI":"10.1002\/asia.70609","type":"journal-article","created":{"date-parts":[[2026,2,3]],"date-time":"2026-02-03T02:49:54Z","timestamp":1770086994000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Effect of Halogen on the Morphology Regulation of Cd\u2010BTC and the Performance of Electrocatalytic Reduction of CO\n                    <sub>2<\/sub>\n                    to CO"],"prefix":"10.1002","volume":"21","author":[{"given":"Jia","family":"Li","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering North Minzu University  Yinchuan P.R.China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tianxia","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering 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