{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,27]],"date-time":"2026-03-27T18:17:45Z","timestamp":1774635465821,"version":"3.50.1"},"reference-count":52,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2026,2,27]],"date-time":"2026-02-27T00:00:00Z","timestamp":1772150400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,27]],"date-time":"2026-02-27T00:00:00Z","timestamp":1772150400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["CRG\/2023\/001415"],"award-info":[{"award-number":["CRG\/2023\/001415"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2026,3]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Supramolecular gels have been developed with flexible network to stabilize species such as flavin mononucleotide hydride with extraordinary short lifetime. In this work, we targeted to stabilize our synthesized radical CP\u2022 (chromenopyridine) in the supramolecular gel network. The rigidity aspects of EPR active multicomponent supramolecular gels were addressed. The gels were obtained from the combination of air stable carbon centered radical DCP\u2022 (dicyanomethylchromenopyridine) and diverse range of aromatic di\u2010\/tri\u2010amine in DMSO and water mixture. During the gel formation, DCP\u2022 was converted into another EPR active molecule CP\u2022. Interestingly, poor solubility of CP\u2022 restricted its direct use in the gel formation with the same set of amines from the similar DMSO and water mixtures. The rheological properties and morphologies of the gels were completely dependent upon the amine nature and solvent ratio. EPR activities of the rigid supramolecular gels remained stable even after H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    treatment. In the case of a selective soft gel with benzene\u20101,3,5\u2010triamine (3), the EPR intensity selectively enhanced after the H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    treatment, due to the formation of DCPC\u2022 formed by reaction of DCPH and in situ formed hydroxyl radical. This radical formation was further validated by the detection of CP\u2010OH adducts from other gel, as confirmed by mass spectrometry.\n                  <\/jats:p>","DOI":"10.1002\/asia.70658","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T11:17:04Z","timestamp":1772968624000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["EPR Active Supramolecular Gel With Network Fabrication: Selective H\n                    <sub>2<\/sub>\n                    O\n                    <sub>2<\/sub>\n                    Induced EPR Enhancement From a Soft Gel"],"prefix":"10.1002","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-8774-3230","authenticated-orcid":false,"given":"Mohit","family":"Kulshrestha","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institution of Technology Roorkee  Roorkee Uttarakhand India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Reena","family":"Kyarikwal","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institution of Technology Roorkee  Roorkee Uttarakhand India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5891-951X","authenticated-orcid":false,"given":"Kalyan K.","family":"Sadhu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institution of Technology Roorkee  Roorkee Uttarakhand India"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2026,2,27]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/B606046N"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2016.54"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202100274"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c06104"},{"key":"e_1_2_8_6_1","article-title":"Communication and Cross\u2010regulation between Chemically Fueled Sender and Receiver Reaction Networks","volume":"123","author":"Sun M.","year":"2022","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/b820283b"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35008d"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2206"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4474"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00078B"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00495E"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00948B"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1MH01117K"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-021-00302-2"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202301223"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja503363v"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.3390\/gels5010015"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c02096"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SM01301D"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.7b03449"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c10039"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202106208"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202310582"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c17146"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.213792"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c06395"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c01608"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2021.06.024"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaenm.3c00697"},{"key":"e_1_2_8_31_1","doi-asserted-by":"crossref","unstructured":"L. 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