{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,22]],"date-time":"2026-10-22T17:41:59Z","timestamp":1792690919900,"version":"4.5.0"},"reference-count":32,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2026,7,6]],"date-time":"2026-07-06T00:00:00Z","timestamp":1783296000000},"content-version":"vor","delay-in-days":5,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2026,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    With growing demand for safe and sustainable energy\u2010storage systems, aqueous zinc\u2010ion batteries (AZIBs) are emerging as promising candidates due to their non\u2010flammable electrolytes and environmental benignity. However, their practical deployment is hindered by sluggish Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transport and electrode instability. In this work, we examine the influence of composition on Zn\n                    <jats:sup>2+<\/jats:sup>\n                    storage in Prussian Blue Analogue (PBA) positive electrodes\u2010 Na\n                    <jats:sub>2<\/jats:sub>\n                    CuFe(CN)\n                    <jats:sub>6<\/jats:sub>\n                    \u00b7yH\n                    <jats:sub>2<\/jats:sub>\n                    O (Cu\u2010PBA), Na\n                    <jats:sub>2<\/jats:sub>\n                    CoFe(CN)\n                    <jats:sub>6<\/jats:sub>\n                    \u00b7yH\n                    <jats:sub>2<\/jats:sub>\n                    O (Co\u2010PBA) and the mixed\u2010metal Na\n                    <jats:sub>2<\/jats:sub>\n                    Co\n                    <jats:sub>0.5<\/jats:sub>\n                    Cu\n                    <jats:sub>0.5<\/jats:sub>\n                    Fe(CN)\n                    <jats:sub>6<\/jats:sub>\n                    \u00b7yH\n                    <jats:sub>2<\/jats:sub>\n                    O (CoCu\u2010PBA). Guided by theoretical calculations, CoCu\u2010PBA exhibits the most favorable Zn\n                    <jats:sup>2+<\/jats:sup>\n                    intercalation behavior, delivering 58 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 100\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . For the negative electrode, Zn\u2010vanadate (Zn\n                    <jats:sub>x<\/jats:sub>\n                    V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    \u00b7yH\n                    <jats:sub>2<\/jats:sub>\n                    O, ZnVO) with its expanded ion\u2010diffusion channels and lower band gap compared to V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    , provides enhanced diffusion pathways and achieves 80 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 100\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . A full AZIB cell assembled using CoCu\u2010PBA and ZnVO with a ZnSO\n                    <jats:sub>4\u2013<\/jats:sub>\n                    silica gel electrolyte delivers a specific capacity of 49 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    (@100\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), an energy density of 61\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    (@125\u00a0W kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), a power density of 612\u00a0W kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    (@18\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and excellent cycling stability (92% retention over 500 cycles at 300\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). These findings highlight an optimized electrode\u2013electrolyte design for advancing high\u2010performance AZIBs.\n                  <\/jats:p>","DOI":"10.1002\/asia.70869","type":"journal-article","created":{"date-parts":[[2026,7,6]],"date-time":"2026-07-06T15:35:14Z","timestamp":1783352114000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Fast Zn\n                    <sup>2+<\/sup>\n                    Transport in Aqueous Zinc Ion Batteries: A Composition\u2010Activity Analysis of Prussian Blue Analogues as Positive and Hydrated Zinc Vanadate as Negative Electrode Materials"],"prefix":"10.1002","volume":"21","author":[{"given":"Arijit","family":"Dey","sequence":"first","affiliation":[{"name":"Department of Chemistry Presidency University\u2010Kolkata  Kolkata 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